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% Purpose: Proposal for NSF Arctic Natural Sciences (ANS) Dirty Snow project

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% 2006 NSF Arctic Research Opportunities (ARO):
% NSF 06-603
% Office of Polar Programs (OPP)
% Arctic Sciences Section (ASS)
% Arctic Natural Sciences (ANS) Program
% Program Manager, ANS: Jane V. Dionne ``die-on'', (703) 292-7427, jdionne@nsf.gov
%                       William J. Wiseman, Jr.    (703) 292-4750, wwiseman@nsf.gov
% Deadlines: Full Proposal 20061208
% NSF FastLane Temporary Proposal # 6633880 PIN 
% NSF FastLane Proposal #0714088 (refer to as ARC-0714088)
% Total 3-year budget request: $518,482
% Project duration: 20070901--20100831
% Annual progress report deadlines: 20080831, 20090831, 20081130
% Procurement control number (PCN): 
% UCI account number: 9-number-fund-sub-object = 9-123456-12345-1-1234 = 9-445925-12345-1-1234 
% Physical Sciences budget code: 1234

% 2005 NSF OPP ARO ANS Round1:
% Due December 15, 2005
% 2006 NSF OPP ARO ANS Round2:
% Due December 8, 2006
% 2006 NSF OPP ARO ANS Round3:
% Due November 10, 2007

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\begin{document}

% Arctic Natural Sciences (ANS)
\def\prpttl{Snow Process Studies and Modeling to Improve Arctic Climate Prediction\\}
\def\prpttllikeboring{Integrating More Realistic Snow Processes into Climate Models to Improve Understanding and Prediction of Arctic Climate\\}
\def\prpttlnot{Improving Understanding and Prediction of Arctic Climate
  by Representing Snow Lifecycle Processes\\}  
\def\prpttlrecent{Upscaling Snowpack Processes to Improve Detection, Attribution, and Prediction of Arctic Climate Change\\}  
\def\prpttlold{Dirty Snow on Land, Glaciers, and Sea-Ice: Understanding
 Arctic Absorbing Aerosol Forcing and Feedbacks\\}  
% Interdisciplinary Research (IDS)
\def\prpttlids{Dirty Snow: Absorbing Aerosol Effects on Cryospheric Climate Sensitivity and Surface Hydrology\\}
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{\noindent%
Web: \url{http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf}\\
NSF Arctic Natural Sciences (ANS) Proposal \href{http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0714088}{ARC-0714088} \hfill Submitted: December~8, 2006\\
Last modified: \today, \xxivtime \hfill Awarded: September~5, 2007}
\begin{center}
\textbf{\Large\prpttl}
\bigskip
Dr. Charles S. Zender \hfill \\
Department of Earth System Science \hfill \\
University of California, Irvine \hfill \\
\end{center}
\vskip 0.5 cm

\noindent\textbf{Information for potential collaborators:}
This NSF proposal responds to the 2006 NSF Arctic Research
Opportunities (ARO) announcement, 
\href{http://www.nsf.gov/publications/pub_summ.jsp?ods_key=nsf06603}{NSF 06-603}.
The proposal was submitted to the 
Arctic Natural Sciences (ANS) Program of the
Division of Arctic Sciences (ARC) in the
Office of Polar Programs (OPP).
The cognizant Program Managers are 
Bill Wiseman \url{wwiseman@nsf.gov}, (703)~292-4750 and 
Jane~V. Dionne \url{jdionne@nsf.gov}, (703)~292-7427.
\medskip

\noindent\textbf{News/Preface:} 
\begin{revnumerate*}
\item 20071111: Filled out IPY participant information form for Polar
  Field Services (NSF contractors).
  Identified website for initial dissemination of LGGE
  snow measurements as \url{http://dust.ess.uci.edu/snw}.
  Identified IPY sub-disciplines as Snow physics, aerosol-climate
  interactions, cryosphere-radiation interactions.

\item 20070907: The award to UCI is official.
  The approved budget is $\$135634 + \$194447 + \$188401 = \$518482$.
  The award dates are 20070901--20100831 (pending successful annual reviews).
  The report due dates are 20080531, 20090531, and 20080831.
  The report overdue dates are 20080831, 20090831, and 20081130.

\item 20070905: Received award letter describing award context and panel review.
  This proposal was one of 188 submitted proposals for 105 distinct projects
  that requested a total of \$75M from the NSF OPP/ARC/ANS in 2006.
  The panel review is the joint evaluation by both ANS and CLD.
  The available ANS budget for all awards was \$8M for three years.
  GEO/ATM/CLD will co-fund this grant.
\item 20070806: Received word that NSF OPP/ARC/ANS and GEO/ATM/CLD (J.~Fein)
  jointly reviewed and recommended funding this proposal. 
  No mention of budget constraints so grant may (knock on wood)
  be fully funded (\$518,482). 
\item Version submitted on December~8, 2006 is NSF proposal 
  (\href{http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0714088}{ARC-0714088})
\end{revnumerate*}

\noindent\textbf{Ideas for Renewals/Extensions/SGERs:}
\begin{enumerate*}
\item Student participation in field IPY experiments (POLARCAT/Greenland!)
\end{enumerate*}

\noindent\textbf{Points considered/addressed since 2006 rejection:}
\begin{enumerate*}
\item Respond to Panel Review Points:
\begin{enumerate*}
\item Evaluate against actual BC/dust-induced melt: Warren measurements
\item Interpretation of satellite pixels containing water and snow: Painter
\item Pan-Arctic issues: non-Greenland field measurement sites? Barrow?
\end{enumerate*}
\item Improve questions for BC tasks in 2007 submittal:
\begin{enumerate*}
\item Do industrial emissions reductions reproduce 1985--2005 Arctic BC decrease?
\item When do current ramps suggest historic Arctic BC highs?
\end{enumerate*}
\item Improve sea-ice questions/tasks in 2007 submittal:
\begin{enumerate*}
\item Examine feedback between aerosol/GHG-induced warming and
  increases in downwelling longwave due to water vapor, atmospheric dust
\item Mesh with Bruce Briegleb and Bonnie Light for sea-ice RT? (and
  obtain upcoming NCAR tech.~note) 
\item Recognize potential ocean role in causing sea-ice asymmetry
\end{enumerate*}
\item Needed In~situ and lab measurements in 2007 submittal:
\begin{enumerate*}
\item Need co-val  $\tpt$, TG, $\dns$, $\rfl(\wvl)$ for, say, two
  weeks each season \textit{in the Arctic}? (will lack SSA without Domin\'{e})
\end{enumerate*}
\item New Budget in 2007:
\begin{enumerate*}
\item Spring/summer Field seasons in Greenland for comprehensive
  SNICAR-closure measurements?  
\end{enumerate*}
\item Letters of Support changes for 2007:
\begin{enumerate*}
\item Get Painter
\end{enumerate*}
\item Newer references and ideas to incorporate where appropriate:
\begin{enumerate*}
\item Francis and Hunter Eos 87(46) 20061114: Sea ice retreat
\item \cite{ACH05}: dirty snow speeds up worst case scenarios presented here
\item \cite{QuH05}: Partitioning surface/atmosphere contributions to polar albedo underestimates surface-mediated feedbacks
\item \cite{AJM04}: SNTHERM model performance on sea-ice
\item \cite{HaQ06}: Using seasonal SAF to estimate GCC SAF
\item \cite{AHK06}: dust deposition on snow
\item \cite{PHM02}: increasing river discharge to Arctic
\item \cite{PeM95}: dust-ice sheet connections
\item \cite{LaS05}: permafrost
\item \cite{DTS05}: incorporate frost flowers, diamond dust, surface hoar in SNICAR
\item \cite{PDT01}: snow algae
\item \cite{Roe06}: AR4 snow albedo evaluation
\item \cite{AnG06,HGG06}: Brown organic carbon
\item \cite{TPH05}: LGM fire emissions
\item \cite{KBB06}: LGM dust melts Asian ice
\item \cite{BWW05}: Surface albedo over sea ice
\item \cite{HWB06}: Antarctic BRDF
\item McConnell et~al. recent ice core dust concentrations?
\item Large-scale snow-fraction representations?
\end{enumerate*}
\end{enumerate*}

\noindent\textbf{News/Preface:} NSF 05-979, Synthesis of Arctic System
Science (SASS), due 20060316, was well suited to study integrated
dirty snow impacts in Alaskan tribal environments, including: 
waste site incineration impacts on local snowpack/permafrost. 
Look at update?

\tableofcontents
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%\markleft{Dirty Snow}
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%\begin{center}
%\textbf{\large\prpttl}
%\end{center}

\begin{center}
\textbf{\Large\prpttl}
\bigskip
Dr. Charles S. Zender \hfill \\
Department of Earth System Science, University of California, Irvine \hfill \\
Collaborators: Florent Domin\'{e}, Elizabeth Hunke, Dorothy Koch, Phil Rasch, Steve Warren
\end{center}

\noindent{\large{\textbf{Project Summary.}}}\label{sxn:smr}
%\enlargethispage*{0.5in}

\textbf{Scientific Merit:}
Greenhouse gas (GHG) forcing alters the rate of snow coarsening and
albedo evolution, influencing snow and sea-ice seasonality.
The prevalence of bright surfaces (snow, glaciers, sea-ice, and
clouds) make the Arctic vulnerable to radiatively induced effects of
snow and ice impurities such as light absorbing carbon (LAC) and
mineral dust (MD).
Coordinated International Polar Year (IPY) activities will yield
pan-Arctic measurements of surface snow properties and of impurity 
concentration, chemical composition, and optical properties which
will help identify regions and seasons most affected by aerosol-driven 
ice-albedo feedback. 

This project uses IPY measurements to improve cryospheric models
used to understand and to predict pan-Arctic climate and climate
change.  
We will
(1)~Use IPY field and lab measurements to improve representation of
snowpack microphysical processes including melt scavenging, hoar
formation, and impurity effects; 
(2)~Implement and/or refine these processes in Arctic land,
atmosphere, and sea-ice components of an Earth System Model (ESM);
(3)~Use the ESM to upscale and better quantify the efficacy of and
response to Arctic climate forcing agents in the 20th and 21st
centuries.

We have integrated surface snowpack evolution and satellite-derived
LAC emissions into a unified modeling framework with which we forecast 
and hindcast contemporary and 21st century climate with and without
prescribed and predicted GHG and aerosol forcing and feedbacks.
IPY measurements gathered by collaborators and by us will help
constrain and evaluate multiple processes in our SNow, ICe, and
Aerosol Radiative model (SNICAR) including snowpack evolution,
aerosol precipitation- and melt-scavenging, and snowpack heating by
impurities. 
We will use the ESM with self-consistent aerosol and snow lifecycles 
to distinguish the relative roles of aerosols and GHGs as Arctic
forcing agents.  

Our scientific questions include:
1.~How do surface hoar and melt/freeze cycles interact in diurnal and
seasonal features in Arctic snowpack specific surface area and
reflectance?  
\csznote{
1.~Are isothermal and temperature-gradient snow aging processes 
sufficient to reproduce diurnal and seasonal features in Arctic
snowpack reflectance?} % end csznote
2.~What are the relative efficacies of aerosol- and GHG-driven 
snow forcing on land and on sea-ice?  
3.~Could plausible LAC emissions reductions significantly mitigate
Arctic climate change?
These questions will be addressed in pre-industrial, present day, and
next century contexts.
The results will improve understanding of ice-albedo feedbacks
crucial to Arctic climate and climate change.

\csznote{
ESM experiments forced by the MODIS-derived Global Fire Emissions
Database (GFED) and fossil fuel (FF) and biofuel (BF) emission record  
(extrapolated through the 21st century)

Explaining LAC decreases from the 1980s to the present, and
hindcasting the strongest IPY-observed biomass burning plumes.
We hypothesize that Arctic LAC and dust cause similar ice-albedo
feedback amplification over glaciers and sea-ice.   

We will support the IPY POLARCAT project by modeling Arctic soot
concentration and snow reflectance following boreal fires.
Snowpack specific surface area, albedo, crystal density,
LAC concentration, LAC melt scavenging, and aging processes  
will (continue to) be evaluated against Arctic \textit{in~situ}
measurements.  
} % end csznote

\textbf{Broader Impacts:}
Snow pervades the Arctic, and our integrated framework for snow
thermodynamic, radiative, and hydrologic processes will contribute to
Arctic research areas including basin and catchment hydrology, 
snow chemistry, snow remote sensing, sea-ice lifecycle, paleoclimate
sensitivity, and glacier mass balance. 
Contributions to the fifth IPCC climate assessment will include more
realistic snowpack processes.
This project trains one graduate student and involves one post-doc in
Arctic aerosol-climate interactions, opens a year-round undergraduate
research position to under-represented minorities, and establishes
strong international research links. 
PI Zender will incorporate this Arctic climate change research into
a K--12 teacher training program and into presentations for lifelong
learning students.
\clearpage
\csznote{
\begin{center}
\textbf{\Large \prpttl}
\end{center}
} % end csznote
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\section{Introduction}\label{sxn:ntr}

The Arctic climate system is experiencing unprecedented change    
due to greenhouse-gas (GHG) induced warming, Arctic haze, and other
factors \cite[]{ACIA05}. 
Global emissions of light absorbing carbon (LAC) aerosol from fossil
fuel sources, a contributor to Arctic haze and ``dirty snow'', 
have steadily increased for decades \cite[][]{PAA01,BSY04}.
LAC emissions from boreal fires are highly variable, and expected,
though with less certainty, to increase as boreal forests warm and
expand northward \cite[][]{RLF06}. 

Current understanding of Arctic LAC climate impacts derives mostly
from studies which focus on LAC direct atmospheric radiative forcing
and which neglect or drastically simplify surface LAC interactions.  
Bright surfaces (snow, glaciers, sea-ice, and clouds) make the Arctic
uniquely susceptible to radiatively induced effects of surface LAC and
dust such as ice-albedo feedback amplification. 
Such feedbacks make dirty snow more efficacious than greenhouse gases
at atmospheric temperature change \cite[][]{HaN04}.  
Dirty snow feedbacks change throughout the aerosol lifecycle in the
complex Arctic environment of snowfall, snowpack aging, snow-melt,
drainage, and analogous sea-ice processes
\cite[e.g.,][]{LEM98,AHH03,FlZ06}.   
Our goal is to assess absorbing aerosol interactions in the coupled
Arctic climate system using models which represent the complex surface
lifecycles of Arctic snow, LAC, and dust, and which have been evaluated
against satellite, in-situ, and laboratory measurements.  

Many use the terms soot and BC interchangeably to denote the light
absorbing component (LAC) of carbonaceous aerosol for historical
reasons or for succintness \cite[e.g.,][]{BoB05}. 
Fossil fuel (FF) and biomass burning (BB) emissions release different
ratios of Black Carbon (BC) to Organic Carbon (OC) aerosols to the
atmosphere.
Complicating matters further, much OC aerosol scatters brightly like
sulfate, but some OC aerosols is light-absorbing and has been termed
``Brown Carbon'' \cite[]{AnG06,HGG06}.

Interest in BC effects on climate, particularly Arctic climate, has
increased as general circulation model (GCM) aerosol capabilities and
emission inventories have improved.  
Recent noteworthy studies suggest that anthropogenic soot may have
caused one quarter of last century's observed warming
\cite[][]{HaN04}, and significant reductions in Northern hemisphere
albedo and sea-ice extent \cite[][]{Jac04}. 
Such estimates are extremely sensitive to accurate treatment of
snowpack aging and radiative transfer \cite[][]{FlZ06,FZR07}, 
as well as uncertainties in boundary conditions such as emissions
and meteorology. 
This project devotes significant attention to improving model
physics based on measurements, and to quantifying model uncertainties
by replicating simulations in two different models.

Ice-albedo feedback is arguably the most important positive feedback 
in the polar climate system \cite[e.g.,][]{Har94,HoB03,QuH06}.
However, we are unaware of any coupled global models that account for
realistic snow processes, including aerosol radiative interactions,
throughout the surface Arctic.    
It is not premature to assemble such integrated models to assess,
predict, and improve understanding of the Arctic climate, so long as
the increased model complexity is justified by continuous demonstrated
fidelity to laboratory and field physical process studies.
Our project coordinates laboratory snow process studies with snow
model development, and larger scale models with collaborator and
community IPY measurements, to study the Arctic response to aerosol
and GHG forcing now, in the past, and in the future. 

\csznote{
\begin{enumerate*}
\item Interpreting historical changes in sea-ice extent and fraction
\item Potential for Arctic BC to disrupt summertime sea-ice concentration
\item Role of extreme Boreal fire years in Arctic reflectance
\item Use coordinated suite of NASA measurements
\begin{enumerate*}
\item MODIS
\item MISR
\item AMSR-E
\end{enumerate*}
\end{enumerate*}
} % end csznote

% Dusty snowpacks provide additional meltwater on Earth and
% probably other planets \cite[e.g.,]{Clo87}

%\subsection{Organization}\label{sxn:org}
This proposal is organized as follows.
The project's historical and scientific context is in
Section~\ref{sxn:bgr}. 
Our scientific objectives and specific hypotheses are in
Section~\ref{sxn:obj}.
Section~\ref{sxn:mth} describes the models and observations we will
use to reach these goals.
Section~\ref{sxn:crd} summarizes the project plan, personnel
responsibilities, time-line, milestones, and travel.
Section~\ref{sxn:prr} describes the results of our relevant, prior
NSF-funded research.
Projects related to ours, potential broader scientific impacts, and
our education plan are in Section~\ref{sxn:mpc}.
Six letters of support/collaboration and a list of acronyms and
abbreviations appear at the end as supplementary documents. 

\section{Background}\label{sxn:bgr}

\subsection{Relevance and Historic Trends}\label{sxn:hst}
Bright surfaces (snow, glaciers, sea-ice and clouds) make the Arctic
uniquely susceptible to ice-albedo feedbacks 
\cite[e.g.,][]{ClN85,HoB03,HaN04,QuH06} 
including those caused and amplified by radiatively induced effects of
surface BC and dust (Figure~\ref{fgr:fdb_dgm}).  
\begin{floatingfigure}[r]{0.5\hsize} % begin Figure~\ref{fgr:fdb_dgm}
%\begin{figure}
%\centering % \centering uses less vertical space than center-environment
\includegraphics*[width=0.95\hsize,angle=0,clip=true,trim=1.0in 1.4in 1.0in 1.0in]{/data/zender/fgr/snicar/sot_snw_fdb}%
\caption[Snow-albedo feedback schematic]{
Snow- (and ice-) albedo feedbacks described in text.
Pink and Red symbols denote moderate and strong positive feedback
loops, respectively.
Plusses and minuses indicate response of target (arrow-head) to
positive change in source (arrow-tail). 
Absorbing aerosols amplify the grain-size feedback with gain~$\GGG$.
\label{fgr:fdb_dgm}}
%\end{figure}
\end{floatingfigure} % end Figure~\ref{fgr:fdb_dgm}
The ``classic'' snow/ice-albedo feedback refers to the snow/ice area 
feedback (upper left loop) that results from changes in the areal
extent of snow/ice cover that conceals the underlying surface.
The reflectances of snow, glacier, and sea-ice contrast enough so
that significant snow/ice-area feedback occurs among these forms of 
frozen water \cite[][]{BWW05,FZR07}.
The temperature grain-size feedback is a weaker positive feedback
(center loop) that arises from temperature controls on snow aging and
on the snow grain size distribution which in turn determine solar
reflectance \cite[]{FlZ06}. 
Internally and externally mixed snowpack impurities darken snow albedo
directly (top right, this is a forcing not a feedback), effectively
increasing the gain $\GGG$ on the temperature-grain size feedback by
heating the snowpack.
Accumulation of hydrophobic impurities at the surface during melt
events may cause a feedback between temperature and soot concentration
(dashed lower right loop) observed by \cite{ClN85} and \cite{CGR96}. 
This melt-impurity feedback is thought to affect hygrophilic aerosol
(e.g., sulfate-coated BC) more than hygrophobic aerosol (e.g.,
uncoated dust).

Representing the vertical distribution of heating in a multi-layer
snow or ice medium is important, not least because the penetration
depths of visible and near-infrared (NIR) radiation into snow
are significantly different \cite[]{WiW80}.
Turbulent heat fluxes and sublimation to the atmosphere can
efficiently dissipate surface-layer ($\lesssim 1$\,\cm) snowpack
radiative heating but not sub-surface heating.
Since snow has low thermal diffusivity that allows sub-surface heating 
to slowly warm the snowpack and accelerate melt onset.
\cite{FlZ05} showed that representing snowpack as multi-layer,
regardless of snow-aging, substantially improves snowpack simulations
in the Tibetan Plateau region.

Mineral dust can also play an important role in the Arctic, far
from its dominant sources in the sub-tropical deserts
\cite[][]{PGT02,ZBN03}. 
Dust is the dominant absorbing aerosol in Arctic ice cores on
interglacial timescales \cite[e.g.,][]{RaK97,FWJ99}. 
Dust embedded in Arctic ice cores records global climate change 
\cite[e.g.,][]{AAG98,KoH01} and marks abrupt climate changes
\cite[e.g.,][]{All00}. 
Numerous studies speculate that in addition to recording climate, 
dust changes climate by (among other things) darkening the
cryosphere \cite[][]{PeM95,AWL00,HKR01,KBB06}.
Present day observations in the Rockies show that dusty snow
accelerates snow melt in some mid-latitude regions (Dr.~Tom Painter,
NSIDC, personal communication).  

Net BC impacts on the Arctic will likely increase through the
21st century. 
BC emissions from combustion, the primary source of Arctic BC
\cite[]{KoH05} have increased with fuel use over the past several
decades, and are known to within a factor of about two \cite[][]{BSY04}. 
Some scenarios project an increase in anthropogenic BC emissions of
30--250\% in the 21st century \cite[][]{NAD00}.
Biomass burning emissions may increase due changes in fire regime
though this is highly uncertain \cite[]{TPH05,VRG06}. 
Present day dust emissions and deposition are known to no better than
about a factor of four globally \cite[]{ZMT04}.
Whether there is currently a trend in global mineral dust emissions 
is not known---increasing (from anthropogenic activities) and
decreasing (due to \COd\ fertilization of vegetation) trends are 
both plausible \cite[]{MaL03,TWH04}. 

Aerosols, absorbing or not, can significantly alter cloud reflectivity
and lifecycle \cite[e.g.,][]{CLV96,ATS00}.
Since aerosol-cloud indirect effects are poorly constrained and are
not a focus of this project, they will not be mentioned again. 
This does not imply that will ignore aerosol-cloud direct and
semi-direct effects.
Aerosol-cloud direct and semi-direct effects are analogous to the
snow/ice-impurity feedbacks mentioned above, and will be treated
thoroughly and consistently throughout the project. 

\csznote{
The increased aridity, equator-to-pole temperature gradients, exposed
continental shelves, and peri-glacial dust generation in past glacial
climates make dust a remarkable climate proxy \cite[][]{RSK97,MML06}.

Estimates of past and future dust emissions contain large
uncertainties including those due to land use change and to \COd\ 
fertilization of vegetative cover \cite[e.g.,][]{MaL03,TWH04}
} % end csznote

\csznote{
We study Arctic climate-snow-aerosol interactions within a coupled
general circulation model (GCM) framework (Section~\ref{sxn:mdl}). 
Using this tool, we estimate Boreal fire emissions changes from 1997
to 1998 increase surface snowpack radiative forcing in the Arctic by
about~50\% \cite[][]{FZR07} (Figure~\ref{fgr:frc_sfc}). 
\begin{floatingfigure}[r]{0.5\hsize} % Begin Figure~\ref{fgr:frc_sfc}
\centering % \centering uses less vertical space than center-environment
%\includegraphics[width=0.4\hsize,angle=270,clip=true,trim=0.0in 0.0in 0.0in 1.5in]{/data/zender/fgr/snicar/sotfrc_sfc_1997f11_JJA}%
\includegraphics[width=0.4\hsize,angle=270,clip=true,trim=0.0in 0.0in 0.0in 0.0in]{/data/zender/fgr/snicar/sotfrc_sfc_1998f11_JJA}%
\caption[Snowpack soot direct radiative forcing]{
Summertime mean surface direct radiative forcing [\wxmS] by soot in
snowpack during 1998, a strong boreal burn year.
\label{fgr:frc_sfc}}
\end{floatingfigure} % End Figure~\ref{fgr:frc_sfc}
These estimates contain many uncertainties and potential Arctic
aerosol-related biases including transport and deposition, size
distribution, optical properties, aging, and cloud interactions. 
These longstanding issues are targets of ongoing research and
International Polar Year (IPY) activities such as POLARCAT
(Section~\ref{sxn:polarcat}).
} % end csznote

\subsection{Absorbing Arctic Aerosol in Models}\label{sxn:mdl}
The fundamental physics of snowpack-aerosol radiative interactions
have been understood for over 25~years \cite[][]{WiW80,WaW80,Clo87}.
However, few GCMs explicitly account for these effects so the
potentially important polar climate amplification of dirty snow is
largely unstudied.
Models which do not explicitly account for absorbing aerosol may
prescribe snowpack darkening as a function of time since last snowfall
\cite[e.g.,][]{ODB04}. 
This approach is consistent with observations that snowpacks darken
with time due to decreasing snow grain specific surface area (SSA) and 
to increasing impurity concentration (e.g., BC deposition) 
\cite[e.g.,][]{WaW80,AHH03} (Figure~\ref{fgr:niwot}).
\begin{floatingfigure}[r]{0.5\hsize} % begin Figure~\ref{fgr:niwot}
\centering % \centering uses less vertical space than center-environment
\includegraphics[width=\hsize,angle=0,clip=true,trim=0.0in 0.1in 0.0in 0.0in]{/home/zender/ppr_FlZ06/fgr_niwot2}%
\caption[Niwot Ridge albedo decay]{
Observed (black) and modeled (color) albedo decay at Niwot Ridge
following the January~2, 2001 snowfall event \cite[]{FlZ06},
for varying SNICAR snowpack temperature gradients.
Error bars represent one standard deviation of all measurements
comprising each day's albedo change.
\label{fgr:niwot}}
\end{floatingfigure} % end Figure~\ref{fgr:niwot}
The observed 0.05 snowpack albedo change within four days at Niwot
Ridge illustrates the important role of snowpack aging in controlling
surface energy budgets. 
Prescribed snowpack aging can capture this aging effect on timescales
of a few days.
More sophisticated physics are required to represent longer timescale
albedo evolution \cite[][]{FlZ06}. 

Single layer models are significantly limited in their representation
of aerosol transport and removal mechanisms and in correctly
representing sub-surface radiative heating and melt.
\cite{FlZ05} studied the vertical distribution of solar radiant
heating on snowpack.  
Using accurate radiative transfer methods in a multi-layer snowpack
model (Section~\ref{sxn:snicar}), we showed that 20--40\% of solar
heating occurs beneath the top 2\,\cm\ of typical snowpack.
This sub-surface heating can cause internal snowpack melt.
Normally, though not always, modeled internal melt occurs in 
conjunction with surface melt. 
Internal snowpack absorption in warm snow can melt snow more
efficiently per unit absorption than surface snowpack absorption
which, in the Arctic, is typically balanced by strong sensible heat
fluxes due to cold overlying air \cite[]{MPB04,FlZ05}.
It may take many sunny days to accumulate enough heat from the small, 
instantaneous solar flux divergence within snowpack \cite[]{BrW93} to
warm interior snowpack to the melting point.
Snow insulation keeps the internal snowpack warmer than the surface
so that radiatively-induced internal warming can trigger the moderate
snow-grain size-feedback loop (Figure~\ref{fgr:fdb_dgm}) until 
melting triggers the stronger snow-cover feedback loop.
%However, all GCMs because they confine solar absorption to the top
%snow layer.   

Today's most sophisticated snow and ice models include Arctic
soot, and, less frequently, dust \cite[][]{HaN04,Jac04,KBB06,FZR07}.
Significant soot concentrations in the surface snowpack strongly
absorb visible radiation some of which would otherwise penetrate 
into the snowpack (Figure~\ref{fgr:rfl_spc_rds_ffc}). 
\begin{figure} % Begin Figure~\ref{fgr:rfl_spc_rds_ffc}
\centering % \centering uses less vertical space than center-environment
\includegraphics[width=0.50\hsize,angle=0,clip=true,trim=0.0in 0.0in 0.0in 0.0in]{/data/zender/fgr/snicar/snw_sot_spectral_rfl}%
% Rotate Mark's image by 270 degrees so baselines agree
% epsffit coordinate arguments are: llx lly urx ury in Postscript units (points)
% (lower-left x, lower-left y, upper-right x, upper-right y)
% cd ${DATA}/fgr/snicar;fl_foo='rdsffc_1997f11-1998b11_JJA';cat ${fl_foo}.eps | epsffit -r 33 141 543 725 | epsffit -r 33 141 543 725 | epsffit -r 33 141 543 725 > ${fl_foo}_270.eps
\includegraphics[width=0.50\hsize,angle=0,clip=true,trim=0.0in 0.0in 0.0in 0.0in]{/data/zender/fgr/snicar/rdsffc_1997f11-1998b11_JJA_270}%
\caption[Spectral reflectance of snow; Response of effective radius]{
Left Panel: Spectral reflectance of pure snow and snow 
externally mixed with 200\,\ugxkg\ BC for different snow size
distributions.  
Vertical lines show positions of MODIS Bands 3, 4, and~5
(left-to-right). 
Right panel: 
Predicted change in summertime-mean effective radius $\rdsffc$\,[\um]
of surface snowpack layer due to 1998 boreal fire BC deposition.
Cross-hatching indicates statistically significant changes 
($\cnfstt < 0.05$) relative to simulations without boreal fire soot 
\cite[][]{FZR07}.
\label{fgr:rfl_spc_rds_ffc}}
\end{figure} % End Figure~\ref{fgr:rfl_spc_rds_ffc}
Hence surface soot concentrations can cool the lower snowpack much
as atmospheric soot cools the surface by reducing insolation.
The screening effect of surface soot competes with the
temperature-grain-size feedback (Figure~\ref{fgr:fdb_dgm}). 
Clearly a modeling approach that includes thermodynamic and
aerosol radiative effects on snowpack aging and heating is required to  
understand their combined effects on the Arctic climate system.

\csznote{
Previous representations of absorbing aerosol and snowpack evolution 
in the Arctic have approximated or neglected crucial feedbacks.
This project, in collaboration with others, will result in a more
complex and interactive Arctic system where 
\begin{enumerate*}
\item Sea-ice is sensitive to surface aerosol radiative effects
\item Snow-ice-aerosol interactions are consistent across the cryosphere 
\item Soot is treated as fractal aggregates not spheres
\item Snowpack aging reproduces observed features
\item Glacial dust and boreal fire soot sources are accounted for
%  thermodynamic fixed Qflux sea-ice model in
%  slab ocean (lateral heat transport is prescribed)
%\item Externally mixed soot not internally mixed soot
%\item Provide improvement to global uniform snow grain size assumption
%  for future satellite surface reflectance retrievals.
%\item Goal to monitor Arctic soot/dust concentration from satellites
%No one has retrieved this yet
\end{enumerate*}
} % end csznote

%Absorbing aerosol species like soot and dust are typically not
%carried as prognostic, radiatively interactive tracers in 
%Arctic sea-ice models.
%The Arctic Ocean Model Intercomparison Project 
%(\href{http://fish.cims.nyu.edu/project_aomip/overview.html}{AOMIP})
% \cite[e.g.,][]{UHM05}.

\section{Scientific Objectives and Hypotheses}\label{sxn:obj}

Our studies of Arctic snow-ice-aerosol processes will improve
understanding and representation of ice-albedo feedbacks and polar
climate amplification.
Key scientific questions we will address include:
\setcounter{enmrfr}{0} % Reset reference counter for this list
\begin{enumerate}

\item \enmrfrstp \label{idx_obj_ssa} % begin Objective~\ref{idx_obj_ssa}
\textbf{Objective}: Understand and reproduce hoar formation and
melt/freeze cycle effects on diurnal and seasonal snowpack specific
surface area and reflectance\\ 
\textbf{Hypothesis}: \textit{Observed diurnal and semi-diurnal albedo 
cycles in polar snowpack can be explained by a spectrum of surface
hoar formation interacting with temperature-driven metamorphism,
including melt/freeze cycles.
Zenith angle and temperature effects dominate seasonal albedo changes.}\\ 
Diurnal and semi-diurnal albedo cycles observed in Antarctica
\cite[][]{McH85,Pir04} suggest that snow Specific Surface Area (SSA)  
recharges, or at least decreases more slowly, due to surface hoar 
formation. 
Hoar may darken fresh and brighten old snowpack when the SSA of hoar
(often hollow prisms) is intermediate between these extremes. 
Whether this process can explain the measured albedo cycles will be
tested in a controlled environment, with the results guiding
improvements in our modeled hoar and melt/freeze formulations. 
Our collaboration with Dr.~Florent Domin\'{e} (LGGE/Grenoble, see
attached letter of support) to measure and model SSA changes due to
surface hoar formation and melt/freeze cycles in controlled laboratory 
experiments that mimic Arctic snow is described in
Section~\ref{sxn:lgge}. 

\item \enmrfrstp \label{idx_obj_csn} % begin Objective~\ref{idx_obj_csn}
\textbf{Objective}: Quantify Arctic climate sensitivity to timing 
and location of Arctic soot events\\ 
\textbf{Hypothesis}: \textit{Fuel combustion dominates biomass burning
  as sources of Arctic BC except in very strong boreal burn years.    
  Fire BC efficacy depends strongly on burn month and location.}\\ 
Many of the hypotheses in this project involve the concept of 
Efficacy, defined as the temperature response per unit forcing
relative to the temperature response due to the same forcing by \COd\ 
\cite[]{HSR05}.
Understanding efficacy is particularly important for BC-snow studies
because \cite{HSR05} and \cite{FZR07} find that \textit{soot in
  snow has the highest forcing efficacy of any known climate forcing
  agent.} Soot in snow has $2$--$4 \times$ the forcing efficiency of \COd.
For example, we find that snowpack~BC heating compounded by
snow-albedo feedback can exceed atmospheric~BC surface cooling of
Greenland in strong fire years (Figure~\ref{fgr:mlt_Grn}). 
Knowing in which locations and months fires will have the greatest
forcing efficacy will identify particularly valuable forest and
vulnerable cryospheric regions.

\csznote{
Ice core analyses (Dr.~Eric Saltzman, UCI, personal communication) 
and model simulations \cite[][]{KoH05,FZR07} agree that boreal fires 
are the primary source of BC deposition to Greenland in strong fire
years.
We will convolve ice core records of historic BC deposition to
Greenland with present day spatially explicit BC emissions data
\cite[][]{RVC05} to study maximum changes in Greenland reflectance and
melt due to boreal BC over the past 1000~years.
} % end csznote

\item \enmrfrstp \label{idx_obj_sea_ice} % begin Objective~\ref{idx_obj_sea_ice}
\textbf{Objective}: Identify snow and aerosol interactions with
sea-ice formation, reflectance, seasonality, variability, and trends\\ 
\textbf{Hypothesis}: \textit{Rapid snow aging with warm surface
  temperatures in spring and summer accelerates ablation of annual
  sea-ice, and Arctic BC amplifies amplifies this ablation during
  strong burn years.
  Inter-hemispheric asymmetry in polar BC deposition contributes 
  to the significant differences between Arctic and Antarctic sea-ice 
  trends.}
Despite nearly globally-uniform GHG forcing, summertime Arctic and 
Antarctic sea-ice show asymmetric trends over the last 25~years
\cite[]{FKC01,SMS03,SSF05}. 
While Antarctic sea-ice has shown little trend, summertime Arctic
sea-ice has retreated by more than~15\%.  
\cite{KoH05} speculate that asymmetry between northern and southern 
hemisphere polar BC deposition may explain sea-ice asymmetry.
Our project will represent snow- and sea-ice-albedo feedbacks
(Figures~\ref{fgr:fdb_dgm}) which when forced by the interannual
variability in BC emissions (Figure~\ref{fgr:msn_bc}) and deposition,
may cause some of the asymmetry and recent accelerations in Arctic 
sea-ice reduction. 

\item \enmrfrstp \label{idx_obj_ghg_aer} % begin Objective~\ref{idx_obj_ghg_aer}
\textbf{Objective}: Determine relative efficacies of aerosol- and
GHG-driven snow forcing on Arctic land and sea-ice\\
\textbf{Hypothesis}: \textit{Aerosol-snowpack interactions may cause
  as much Arctic warming as GHGs.}\\ 
\cite{HSR05} estimate that effective global forcing by GHGs since 1750
is about 3.0\,\wxmS, more than ten times greater than their
0.25\,\wxmS\ snow albedo forcing by soot.
% Global soot+dust efficacy is 3.86
% NP2 sncpd05 change in TREFHT=1.1 K, SNOAERFRC=0.33
% ncdiff -O ${DATA}/anl_sncpd05/sncpd05_clm_NP2.nc ${DATA}/anl_sncpd06/sncpd06_clm_NP2.nc ~/sncpd05msncpd06_clm_NP2.nc
% ncks -v SNOAERFRC,TREFHT ${DATA}/anl_sncpd05/sncpd05_clm_NP2.nc
However, we estimate the effective snow-albedo forcing (i.e., efficacy 
times forcing) of soot and dust averaged over the Arctic (north of
67\,\dgrn) is 1.25\,\wxmS, about 40\% of the GHG forcing.
We expect that representing snowpack impurity driven feedbacks
(Figure~\ref{fgr:fdb_dgm}) over sea-ice will further increase the
Arctic climate sensitivity to aerosols relative to GHGs.
Hence the Arctic may be unique as region where total effective aerosol
forcing is positive (not negative) and occasionally (e.g., strong
burn years) exceeds GHG forcing.
If true, this would bolster suggestions that targeted reductions in
industrial and boreal fire emissions may achieve significant
mitigation of Arctic climate change \cite[]{Jac02,Jac04,RLF06}.
Our modeling scenarios will quantify the physical plausibility and
robustness of these arguments.

\csznote{
Multiple lines of evidence support the first hypothesis:
First, representation of thin sea-ice amplifies polar climate
sensitivity \cite[][]{HoB03,HBH06}.
Second, internal snowpack heating amplifies mid-latitude climate
sensitivity \cite[][]{FlZ05}.
Third, aging and absorbing aerosol content increase polar climate
sensitivity \cite[][]{Jac04,HaN04,FZR05}. 
We will test this hypothesis by comparing summer sea-ice retreat with
and without snow aging in CICE. 
} % end csznote

\csznote{
\item \enmrfrstp \label{idx_obj_sot_dst} % begin Objective~\ref{idx_obj_sot_dst}
\textbf{Objective}: Quantify relative roles of Arctic soot and dust 
as polar climate amplifiers\\
\textbf{Hypothesis}: \textit{Industrial soot heats Arctic climate
  more/less than dust in the present/LGM climate.}\\ 
Soot is approximately an order of magnitude more absorptive than 
dust at solar wavelengths.
Dust deposition to Greenland in glacial periods is 2--20 times greater 
than present day \cite[e.g.,][]{RaK97,MML06}, enough to compete with
BC as a snow-albedo trigger.
However, differences between BC and dust deposition seasonality and
variability will modulate the net solar forcing of these aerosols 
on Arctic surfaces.
Dust of Asian provenance \cite[][]{BGR97} will likely deposit more
continually than North American glacial dust \cite[][]{MML06}.
The springtime maximum Asian dust export \cite[][]{ZBN03} is less
efficacious for Arctic forcing than summertime aerosol events.
How these spatio-temporal deposition patterns affect Arctic climate
sensitivity is nearly completely unexplored.
} % end csznote
\end{enumerate}

\section{Tasks: Arctic Models and Observations}\label{sxn:mth}

It is important to emphasize that this project will not develop
any Arctic climate model components from scratch.
Our intellectual efforts are primarily directed toward uncovering
the influence of previously neglected snow-ice-aerosol interactions
in the Arctic system.
All model development tasks outlined below involve improving physics
in our in-house snow-ice-aerosol model (SNICAR) and/or merging these
physics into high-quality Arctic system component models developed
and maintained at national centers.  

\subsection{Community Climate System Model}\label{sxn:ccsm}
An integrated Earth System Model which fully couples aerosols, snow,
atmosphere, ocean, and land/sea-ice is required to test our hypotheses 
(Section~\ref{sxn:obj}). 
We use the NCAR CCSM---its polar climate simulations and biases
are well characterized and continually evaluated against
meteorological analyses and satellite observations  
\cite[e.g.,][]{BrB981,HoB03,HBH06}.

Arctic absorbing aerosols, soot and dust, are primarily emitted from
non-frozen land surfaces at lower latitudes
\cite[e.g.,][]{ZBN03,KoH05}.
As such, these aerosols travel through multiple climate ``spheres'',
i.e., the biosphere, atmosphere, and cryosphere before depositing
to snow.
This project focuses on the cryosphere and we will rely on our
continuing external collaborations to obtain the most realistic
aerosol distributions possible.
The CCSM BC/OC aerosol transport and deposition we use come from long
time collaborators Drs.~Phil Rasch (see attached letter of support)
and Bill Collins (NCAR) \cite[][]{RCE01,CRE01,CRE02}.

Dr.~Natalie Mahowald (NCAR) and PI~Zender are primary developers of
the Dust Entrainment and Deposition (DEAD) mineral dust model
\cite[][]{ZBN03,ZNT03,MLD03} which, embedded in CCSM, predicts the 
Arctic dust deposition fields.
Part of our motivation for including dust affects in the present
day Arctic stems from our preliminary equilibrium simulations of the
Last Glacial Maximum (LGM) that account for glaciogenic dust.
We use the method of \cite{MML06} to obtain simultaneous agreement
between the model and LGM loess, ice core, and marine deposition
records.  
Our preliminary results indicate that glaciogenic dust is very
efficacious at warming LGM Arctic climate and so should not be
neglected without good reasons in present day Arctic change studies. 

\subsection{SNICAR}\label{sxn:snicar}
The project builds upon, extends, and applies our existing,
state-of-the-art, SNow, ICe, and Aerosol Radiative model, SNICAR
\cite[][]{FlZ05,FlZ06}.
SNICAR treats snowpack hydrologic, thermodynamic, and radiative 
processes in a unified manner to explicitly represent feedbacks
between snowpack heating, albedo evolution, densification, melt, and
aerosol concentration (Figure~\ref{fgr:fdb_dgm}).
For climate simulations, SNICAR runs in a host snowpack model which
to date has been the Community Land Model (CLM) \cite[][]{DZD03}.
The CLM uses five vertical snowpack layers \cite[]{ODB04} and itself
runs off-line forced by meteorological analyses or on-line in a GCM. 
We nest CLM/SNICAR in the Community Atmosphere Model (CAM)
\cite[][]{CRB06} modified for prognostic soot and dust emissions.

SNICAR has different capabilities than, and shares some capabilities
with, other the well-known snow models such as SNTHERM
\cite[][]{Jor91,AJM04}. 
SNICAR, designed for climate modeling, is at heart a size-resolved
snow aging model designed above all else to predict snow SSA, and thus 
snowpack optical properties \cite[]{GrW99}. 
SNICAR operates within a host snow-hydrology, thermal, mass-balancing
model (currently CLM). 
SNTHERM includes many more snow and ice thermodynamic processes and
states than CLM, and many fewer radiative features than SNICAR.
To our knowledge, SNTHERM is alway used as a column model, and has
not been embedded in an interactive GCM suitable for Arctic climate  
change studies.

\subsubsection{Snow Aging}\label{sxn:aging}
Compared to the enormous efforts and progress at improving cloud
physics since \cite{CPB89} highlighted its importance, relatively
little effort has gone to improve snowpack representation in climate
models. 
It is not surprising that intercomparison of Arctic climate
simulations identifies snow (mis-)treatment as a leading cause of
inter-model and model-measurement discrepancy \cite[][]{HaQ06,Roe06}.

Some models \cite[e.g.,][]{Jor91,ODB04} consider the role of
temperature in albedo decay.
To our knowledge, though, SNICAR is the only GCM snow model that
considers the dominant role of temperature-gradient driven
metamorphism. 
High-latitude snowpack can have temperature gradients well in 
excess of 100\,\kxm\ owing to strong radiative cooling at the surface 
during night, and good thermal insulation of deeper snow.
Vapor-density gradients induced by these temperature gradients cause
rapid snow metamorphism \cite[][]{StB97}.
Using first principles, SNICAR accounts for the roles of initial size 
distribution, temperature, temperature gradient, snow density, and
inter-particle spacing in the evolution of snow specific surface area 
(SSA) \cite[][]{FlZ06}.
Vapor diffusion from highly-curved surfaces characteristic of fresh, 
dendritic snow plays a smaller, but non-negligible role in grain
growth via the Kelvin Effect in low temperature-gradient environments
\cite[e.g.,][]{Col80}. 
\csznote{
Recent SEM observations of well-sintered snow support the hypothesis
that grain-boundary diffusion is an important mechanism in sintering
\cite[][]{RoS06}, although the importance of this mechanism has been 
discounted in earlier studies.  
SNICAR does not yet explicitly represent sintering.
} % end csznote
\iftskbrk{\clearpage}{} % Break page after each task

\subsubsection{Snow SSA Measurements}\label{sxn:lgge}
The laboratory of Dr.~Florent Florent Domin\'{e} (LGGE/Grenoble, see 
attached letter of support) has produced many of the best controlled
and characterized snow aging measurements.
\begin{floatingfigure}[r]{0.5\hsize} % begin Figure~\ref{fgr:sdn}
\centering % \centering uses less vertical space than center-environment
% Rotate Mark's image by 270 degrees so baselines agree
% cd ~/ppr_FlZ06;fl_foo='lggnx';cat ${fl_foo}.eps | epsffit -r 0 0 282 1020 | epsffit -r 0 0 282 1020 | epsffit -r 0 0 282 1020 > ${fl_foo}_270.eps
\includegraphics[width=\hsize,angle=0,clip=true,trim=1.30in 0.0in 1.30in 0.0in]{/home/zender/ppr_FlZ06/lggnx_270}%
\caption[Isothermal SSA]{
Observed \cite[]{LTD04} and modeled \cite[]{FlZ06} SSA for isothermal
snowpack conditions and varying choices of $\gsd$, the standard
deviation of the modeled particle-pore spacing distribution. 
\label{fgr:sdn}}
\end{floatingfigure} % end Figure~\ref{fgr:sdn}
\noindent They have characterized snow specific surface area (SSA) evolution in
isothermal and temperature gradient conditions
\cite[]{CLD03,LTD04,TDS07}. 
We use the full microphysical results of SNICAR---which runs off-line
with $\sim 200$ snow grain size bins each with $\sim 40$ pore-particle
spacing bins---to compute the free parameters of the compact SSA
expression that they show fits their measurements \cite[]{LTD04}
(Figure~\ref{fgr:sdn}). 
Our resulting parametric  expression for SSA evolution describes
isothermal and temperature gradient snow grain evolution quite well 
\cite[]{FlZ06,TDS07}.

Zender will collaborate with Domin\'{e} at LGGE on a series of SSA
measurements. 
Many studies show that vapor saturation can induce frost deposition of 
small, ornate surface hoar crystals that brighten the surface or at
least retard SSA aging.
This occurs diurnally and may explain daytime semi-diurnal albedo
cycles observed in Antarctica \cite[][]{McH85,Pir04}, but is not
yet represented in SNICAR, which predicts monotonically decreasing
SSA in the absence of fresh snow.
In Fall 2007 we will extend the SNICAR framework to account for
different crystallographic shapes, so that the inter-particle pore
spacing distribution and the ice crystal shape factor (or
``capacitance'') \cite[]{FlZ06} can account for more complex shapes. 
When atmospheric conditions favor surface hoar growth, the model will
allow deposition to form faceted shapes such as hollow columns which
have significantly higher SSA than spheres. 

In Winter 2008 we will measure SSA evolution from local snow 
to gain sufficient data to evaluate the model hoar formulation.
The snow chamber can mimic a wide range of temperatures and
temperature gradients found in the Arctic.  
We are highly interested in characterizing the SSA 
(and snow albedo) evolution response to melt/freeze cycles.
SNICAR now employs an empirical formulation \cite[]{Bru89} outside
the range of its validity.
Our new model formulation for grain size evolution near the melt 
point will be guided by these and other observations
\cite[]{RaT79,LTD04} and Ostwald ripening theory.

The experiments will characterize SSA during diurnal cycles of
ripening to near melt, and then to diurnally repeating melt/freeze
events. 
The resulting parameterization will improve the grain size-albedo
feedback (Figure~\ref{fgr:fdb_dgm}) which is very strong for even
a single melt/freeze cycle.
The influence of the surface hoar and melt/freeze processes on
snowpack and climate will then be assessed in the global model,
with particular attention paid to crucial Arctic transition regimes
such as the ablation zone of glaciers and during melt-back of seasonal
snow regions. 

\csznote{
In Spring 2008 we plan a series of fresh snow SSA measurements
to help answer the question ``What determines the SSA of fresh snow?''
Currently by controlled amounts of snow-impurities.
} % end csznote

In Spring 2008 we plan a series of snow SSA measurements forced by
impurities.
The idea is to compare SSA evolution of snow samples mixed with well 
characterized soot, e.g., the Monarch~71 elemental carbon adopted by
Clarke \cite[e.g.,][]{ClN85}. 
Impurity mass will be weighed before mixing, retrieved using 
reflectance fitting to the model, and can be measured with a total
carbon analyzer.

Standard measurement procedure will include routine visible and near 
infrared reflectances (450 and 1310\,\nm) to simultaneously constrain 
SSA and snowpack absorption.
Selected measurements will be made with higher resolution spectral
radiometers in collaboration with other interested LGGE investigators.
It is worth noting that, to our knowledge, these will be the first
simultaneous snow SSA and reflectance measurements.
These data will provide novel and useful constraints for snow models
such as SNICAR and SNTHERM. 
\iftskbrk{\clearpage}{} % Break page after each task

\subsubsection{Snow Radiation and Optics}\label{sxn:opt}
The off-line microphysical version of SNICAR runs at 10\,\nm\ spectral
resolution in the solar spectrum from 0.3--5.0\,\um\ (470 bands). 
This is useful for simulating narrow-band satellite channels
such as MODIS/MISR channels (Figure~\ref{fgr:rfl_spc_rds_ffc}).
The vertically resolved multi-layer radiative transfer component
\cite[][]{WiW80,TMA89} treats snow as a collection of hexagonal
prisms based on the equivalent surface area-to-volume approximation  
\cite[][]{GrW99,NGW03}.
SNICAR accounts for solar zenith angle, direct and diffuse incident
radiation, reflectance of the underlying surface \cite[][]{DZD03}, 
wet snow metamorphism \cite[][]{Bru89},
and 
vertically-resolved effective radius (\rdsffc),
snow depth, density, and concentrations of absorbing impurities
\cite[][]{WaW80}.  
A lookup table (computed off-line) contains two-stream optical
parameters (single scattering albedo, extinction coefficient, and
asymmetry parameter) as functions of snow SSA and wavelength.

Snow and aerosol optical properties link the snowpack microphysical 
properties (aerosol concentration, particle size distributions)
to macroscopic net absorption (Figure~\ref{fgr:frc_sfc}), 
reflectances (Figures~\ref{fgr:niwot} and~\ref{fgr:rfl_spc_rds_ffc}a),  
and heating rates that drive the snow melt (Figure~\ref{fgr:mlt_Grn})
and temperature change which trigger snow-albedo feedback.
These responses are sensitive to optical property assumptions
which this project will refine, including 
\begin{enumerate*}
\item BC indices of refraction: 
  As per \cite{BoB05}, we use \cite{ChC90} rather than CAM-default 
  OPAC properties \cite[][]{HKS98} for elemental carbon.
  We assume a BC/sulfate core/mantle for hydrophilic BC \cite[]{BHB06}.
\item BC shape: 
  Treating BC as spheres likely underestimates its single scattering
  albedo relative to more realistic shapes such as fractal aggregates
  \cite[][]{Sor01,BoB05}
\item Aerosol mixing: 
  Although existing observations are insufficient to rule out dry
  scavenging as the dominant removal mechanism \cite[]{KoH05}, we  
  think BC and dust in remote regions such as the Arctic are likely 
  deposited primarily by wet scavenging
  \cite[][]{NoC88,CCR01,ZBN03,CSK04,Jac04}  
  Nucleation-scavenged aerosols will often be internally mixed within
  snow grains.  
  We will try an effective medium approximation
  \cite[e.g.,][]{BoH83} to represent internally mixed aerosols. 
  We will also investigate solutions for dark particles in weakly
  absorbing media \cite[]{MaS99} which may be more physically
  defensible for ice particles. 
  All these approaches will increase snowpack absorption relative to
  our current externally mixed assumption.
%\item Darkening by desert and peri-glacial dust sources \cite[][]{MML06}. 
\end{enumerate*}

\subsection{In Situ Observations}\label{sxn:insitu}
Arctic snowpack BC and dust concentrations and optical properties are
key diagnostics that integrate aerosol source, transport, deposition,
with snow aging and melt processes.  
We will obtain new data to evaluate and constrain our models from
collaborators Drs.~Steve Warren (U.~Washington, see attached letter of
support), Tom Grenfell and Tony Clarke (U.~Hawaii) who have an ANS
project ``Black carbon in Arctic snow and ice, and its effect on
surface albedo''. 
\begin{floatingfigure}[r]{0.5\hsize} % Begin Figure~\ref{fgr:frc_sfc}
\centering % \centering uses less vertical space than center-environment
%\includegraphics[width=0.4\hsize,angle=270,clip=true,trim=0.0in 0.0in 0.0in 1.5in]{/data/zender/fgr/snicar/sotfrc_sfc_1997f11_JJA}%
\includegraphics[width=0.8\hsize,angle=270,clip=true,trim=0.0in 0.0in 0.0in 0.0in]{/data/zender/fgr/snicar/sotfrc_sfc_1998f11_JJA}%
\caption[Snowpack soot direct radiative forcing]{
Summertime mean surface direct radiative forcing [\wxmS] by soot in
snowpack during 1998, a strong boreal burn year.
\label{fgr:frc_sfc}}
\end{floatingfigure} % End Figure~\ref{fgr:frc_sfc}
Their project will sample snow and ice from pan-Arctic
locations to update, improve, and extend the BC survey that Clarke and
co-workers conducted in 1983--1984 \cite[][]{ClN85}. 
Warren's team determines BC and dust optical properties from the
samples using filter absorptance techniques.
They will measure in~situ snow density and spectral albedo at selected
sites to enable closure studies of the instantaneous surface solar
radiation field.   

Warren's team is already processing new aerosol-snowpack measurements
from the North Pole observatory, Ellesmere, Hudson Bay, and Greenland. 
By summer 2007, they will have additional data from Greenland, Russia, 
and from Matthew Sturm's 4000\,\km\ traverse of North American tundra. 
The BC/dust measurements from Dr.~Konrad Steffen's Automated Weather
Station (AWS) sites in Greenland \cite[]{StB01} sample strong spatial
gradients in exposure to North American biomass burning plumes
(Figure~\ref{fgr:frc_sfc}) and so will be particularly valuable.  

\csznote{
\cite{FlZ06} and \cite{FZR07} used previous measurements from Warren,
Grenfell, and Clarke to evaluate and to constrain the geographic
distribution of predicted BC mass concentration
(Figure~\ref{fgr:fgr_ppr_sotc}) and snow spectral albedo.
(Figure~\ref{fgr:rfl_spc_rds_ffc}).
} % end csznote

\cite{FZR07} compared CAM/SNICAR simulations to the approximately two 
dozen published Arctic surface snowpack BC measurements, many from
Clarke's 1983--1984 survey.
SNICAR captures the measurements over three orders of magnitude in
concentration with little mean bias though significant RMS bias
(Figure~\ref{fgr:fgr_ppr_sotc}).
Greenland concentrations are typically 1--4\,\ugxkg, and as high
as 30\,\ugxkg\ \cite[][]{SCD02}.  
\begin{floatingfigure}[r]{0.50\hsize} % begin Figure~\ref{fgr:fgr_ppr_sotc}
%\begin{figure}
\centering % \centering uses less vertical space than center-environment
\includegraphics[width=\hsize,angle=0,clip=true,trim=0.0in 0.0in 0.0in 0.0in]{/home/zender/ppr_FZR07/fgr_ppr_sotc_whisker2_clr}%
\caption{Observed and simulated BC concentrations from \cite{FZR07}.
Log correlation is 0.78.
\label{fgr:fgr_ppr_sotc}}
%\end{figure}
\end{floatingfigure} % end Figure~\ref{fgr:fgr_ppr_sotc}
Interestingly, \cite{GLS02} showed that BC concentrations measured
during the SHEBA experiment had decreased significantly since the
early 1980s, \textit{contrary to the increasing trend in global
  emissions}. 
Whether reduced fuel combustion in proximal regions (e.g., former
Soviet Union) can explain this trend could be investigated in our
modeling framework if interannually varying industrial and fire BC
emissions timeseries were extended back to the 1980s.
The new measurements by Warren's project will clarify the spatial
extent of this intriguing result, and provide useful falsification
for errant model interdecadal trends in BC deposition.

In situ measurements will also provide updated constraints on scavenging
coefficients using our models.
Clarke will measure/estimate scavenging coefficients for removal
of atmospheric BC by snow \cite[][]{NoC88} and for removal of snowpack
BC by snow melt \cite[][]{ClN85}.
Meltwater flushing is perhaps the most important BC removal mechanism,
since preferential gravitational settling would be extremely slow
for BC that is externally-mixed.
Qualitative observations suggest that BC may become more concentrated
in surface snow during melt events \cite[][]{WaW80,ClN85}.
\cite{CGR96} spread hydrophobic and hydrophilic BC on top of snow,
and noticed that hydrophobic BC remains in surface snow longer,
maintaining lowered albedo for a longer time.
Because of imprecise knowledge of vertical distributions of BC and
meltwater formation in this experiment, we can only deduce that
hydrophilic BC is scavenged about five times more efficiently than 
hydrophobic BC.
Using a simple $\me$-folding removal model with this data,
we estimate lower bounds for scavenging ratios of 0.01 and 0.002 for 
hydrophilic and hydrophobic BC, respectively.
Even greater uncertainty exists for snow processes on sea-ice.
Dr.~Tom Painter (NSIDC) is conducting studies in the Rockies that will 
help constrain the melt-scavenging efficiency of dust.

We will perform selected closure studies to ensure that SNICAR closely
reproduces the measured spectral reflectance for given snow conditions
and impurity concentrations/properties (measured and estimated by
Warren's team). 
These studies complement Warren's studies in that we also predict snow 
conditions and snow BC/dust concentrations.
Differences between our predictions and the field measurements will
help us identify and correct model physics deficiencies, e.g.,
melt scavenging in SNICAR, frozen precipitation scavenging in CAM. 
Insofar as our predictions and field measurements agree (e.g.,
Figure~\ref{fgr:fgr_ppr_sotc}), our model can upscale the point
measurements to regional or even pan-Arctic estimates of impurity
concentrations, and the consequent radiative forcing and response.
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{Fire}\label{sxn:fire} % Section~\ref{sxn:fire} 
Our model uses the Global Fire Emissions Database (GFED2) which
is derived from fire counts retrieved by MODIS satellite sensors.
GFED2 includes more biomass burning source regions than \cite{CoW96}
and \cite{KoH05} and captures the significant interannual variability
of boreal fire BC \cite[]{VRG06}. 
\begin{floatingfigure}[r]{0.5\hsize} % begin Figure~\ref{fgr:msn_bc}
  \includegraphics[width=0.9\hsize,clip=true,trim=0.10in 0.0in 0.0in 0.1in]{/home/zender/ppr_FZR07/fgr_ppr_bcemis_bw}
\caption{Zonal annual mean BC emissions from fossil fuel+biofuel
  combustion \cite[]{BSY04} and GFED2 biomass burning during 1998 and
  2001 \cite[]{VRG06}.} 
\label{fgr:msn_bc}
\end{floatingfigure} % end Figure~\ref{fgr:msn_bc}
We use prescribed fossil and biofuel BC emissions \cite[][]{BSY04},
and convert GFED2 fire emissions to BC with estimated emissions
factors updated from \cite{AnM01}.   
Using GFED2 and our central estimates of emissions factors, we
estimate that biomass burning BC emissions north of 30\dgrn\ decreased
from 0.8\,Tg to 0.2\,Tg between 1998, a strong fire year, and
2001, a weak fire year (Figure~\ref{fgr:msn_bc}) \cite[][]{FZR07}.
Models driven by satellite-derived emissions agree that fires explains 
the largest component of interannual Arctic BC deposition variability
although whether tropical fire BC or boreal fire BC dominates
Arctic BC variability is disputed \cite[][]{KoH05,FZR07}.

Our simulations suggest boreal fire soot causes seasonal net surface
solar radiation forcings of 0.5--0.75\,\wxmS\
(Figure~\ref{fgr:frc_sfc}) in strong fire years.
These forcings induce feedbacks such as larger snow grain size
(Figure~\ref{fgr:rfl_spc_rds_ffc}) which together increase seasonal
surface absorption by more than 1.5\,\wxmS\ \cite[][]{FZR07}.
Soot-snow feedbacks in strong fire years appear to cause significant
increases in meltwater production in Greenland snowpack
(Figure~\ref{fgr:mlt_Grn}).
\begin{figure} % Begin Figure~\ref{fgr:mlt_Grn}
\centering % \centering uses less vertical space than center-environment
\includegraphics[width=0.33\hsize,angle=270,clip=true,trim=0.5in 1.0in 0.0in 1.75in]{/data/zender/fgr/snicar/qmelt_1997f11-1998b11_JJA_GR}%
\includegraphics[width=0.33\hsize,angle=270,clip=true,trim=0.5in 1.0in 0.0in 1.75in]{/data/zender/fgr/snicar/qmelt_1998f11-1998b11_JJA_GR}%
\includegraphics[width=0.33\hsize,angle=270,clip=true,trim=0.5in 1.0in 0.0in 0.0in]{/data/zender/fgr/snicar/qmelt_1998g11-1998d11_JJA_GR}%
\caption[Snow melt response to snowpack soot]{
Summertime mean change in Greenland snow melt [\mmxday] due to boreal
soot during low (1997, left) and high (1998, middle and right) boreal
burn years.  
Middle panel includes all feedbacks (soot in atmosphere and snowpack), 
while right panel includes atmospheric soot only.
Cross-hatching indicates statistically significant changes 
($\cnfstt < 0.05$) relative to simulations without boreal fire soot
\cite[][]{FZR07}. 
\label{fgr:mlt_Grn}}
\end{figure} % Begin Figure~\ref{fgr:mlt_Grn}
Note that neglecting soot-snowpack interactions (and accounting only
for atmospheric soot effects) eliminates or reverses the sign of most
of the increased snow melt over Greenland. 
Hence, \textit{significant Arctic change is attributable to
  aerosol-snowpack feedbacks not represented in most GCMs}.
We eagerly anticipate results in Year~2 when SNICAR is embedded in a
fully interactive sea-ice model which responds to soot and dust
sources. 
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{Sea-Ice}\label{sxn:cice}
Sea-ice is the fulcrum of Arctic ice-albedo feedbacks.
Snow conditions on and impurities in sea-ice play important roles
in the solar radiation budget of the sea-ice environment
\cite[]{Gre91,GLS02,BWW05}.  
\cite{GLS02} reported that BC mixing ratios in snow on Arctic sea-ice 
increased from the pole ($\sim 5$\,\ugxkg) to the coastal regions 
($\sim 50$\,\ugxkg).
In large-grained snow, 50\,\ugxkg\ lowers broadband snow reflectance by  
$ > 0.03$, a level that begins to exceed typical observational
uncertainties of albedo measurements.

The Los Alamos \href{http://climate.lanl.gov/Models/CICE}{CICE} model 
is the sea-ice component of the CCSM Earth system model.
CICE contains an Ice Thickness Distribution which maintains a
half dozen prognostic categories of ice thickness in each grid cell
\cite[][]{HBH06}.  
However, CICE currently represents snow as a medium with prescribed
albedo with no snow aging nor absorbing impurity representation.
LANL will implement a prognostic aerosol tracer capability into CICE
in early 2007 (E.~Hunke, personal communication, 2006). 

Our collaborator, Dr.~Elizabeth Hunke of LANL (see attached letter of
support), is a CICE principle developer.
\begin{floatingfigure}[r]{0.50\hsize}
\centering
\includegraphics[width=0.9\hsize,angle=270]{/home/zender/prp_IGPP06/fgr_rdsffc}
\caption{Springtime effective grain size (\um) of snow on sea-ice
predicted by SNICAR coupled to a slab-ocean version of the NCAR
CSIM. The colorbar range corresponds to broadband shortwave snow
albedos from $\sim 0.72$--$0.85$.}
\label{fgr:rds_ffc_cice}
\end{floatingfigure}
\noindent With Hunke's guidance, the UCI team will merge SNICAR physics (snow
aging, radiative transfer, snow-aerosol optics) into the multi-layer
snowpack in CICE. 
Climate and aerosol conditions will cause strong regional structure
in snow aging on sea-ice, resulting in a spectrum of snow grain sizes
(Figure~\ref{fgr:rds_ffc_cice}) and thus ice-albedo feedbacks.
The underlying sea-ice will also retain and concentrate soot and dust
deposited directly from the atmosphere and scavenged from melting snow
cover (Figure~\ref{fgr:fdb_dgm}).
We will then test our hypotheses (Objective~\ref{idx_obj_sea_ice}) by   
comparing sea-ice trends with and without snow aging and aerosols.
The snow/sea-ice simulations will be evaluated against available
climatologies such as the National Ice Center 33-year gridded ice
climatology, and satellite products described in Section~\ref{sxn:stl}.

We will couple the snowpack radiative transfer and impurity physics to
the new sea-ice radiative transfer physics module developed by
Drs.~Bruce Briegleb (NCAR) and Bonnie Light (U.~Washington).
Their sea-ice radiation model accounts for for aerosols embedded in
the complex sea-ice-brine matrix (a melt pond representation is under
development). 
Coupling the snow to sea-ice radiative transfer will require replacing
the two-stream solution in SNICAR \cite[]{TMA89} with the
adding-doubling method used in the sea-ice \cite[]{Bri921}.
The adding-doubling method may provide superior performance to two
stream methods in thick snowpacks where transmission is negligible.

Simulated sea-ice reflectance, surface properties, extent and
thickness will then respond to the full lifecycle of Arctic aerosols. 
This will be a significant improvement to current models (including
ours) which remove aerosols from snow and sea-ice with rather ad~hoc
mechanisms to prevent excessive concentrations from accumulating in
multi-year land and sea-ice \cite[][]{Jac04,FZR07}.
Also, SNICAR is sufficiently modular so that all aerosols in CAM can
be easily added to the snowpack lifecycle.
Future experiments will include the effects of light absorbing organic
carbon aerosols termed ``Brown Carbon'' \cite[]{AnG06,HGG06}.
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{Ice Sheets and Glaciers}\label{sxn:glc}
A key shortcoming of this (and other) coupled Arctic modeling projects 
is the absence of realistic ice sheets and glaciers.
Although crucial to the net hydrology (and stability) of the Arctic
climate system, glaciers and ice sheets are not yet fully integrated
into Earth system models. 
LANL scientists are developing an interactive ice sheet component for
the CCSM based on \href{http://wiki.nesc.ac.uk/read/glimmer-project}{GLIMMER} 
\cite[]{Pay99}. 
We will provide SNICAR snow-aerosol physics for LANL's GLIMMER.
Hence we anticipate the CCSM will have a glacier model component
sensitive to realistic snowpack physics and BC interactions by
year~3. 

\subsection{Satellite Observations}\label{sxn:stl} % Section~\ref{sxn:stl}
NASA MODIS, MISR, and AMSR-E retrievals can constrain free model
parameters and help us interpret the regional and seasonal behavior of   
snowpack processes.
Figure~\ref{fgr:rfl_spc_rds_ffc}a shows simulated snow spectral
reflectance expected in visible MODIS bands for various grain sizes.
Soot concentration is most apparent in visible channels and
particle sizes information is most distinguishable in the near
infrared (NIR) \cite[][]{PDR03}, e.g., near MODIS channel~5.
However, soot-in-snow is difficult if not impossible to retrieve 
from satellite. 
The albedo perturbation by 50\,\ugxkg\ soot
(Figure~\ref{fgr:rfl_spc_rds_ffc}), a relatively high Arctic  
concentration (Figure~\ref{fgr:fgr_ppr_sotc}), may not exceed
instrumental noise, surface variability (e.g., sastrugi, leads), and
the signal of clouds and atmospheric soot (S.~Warren, personal
communication, 2006).   
Nevertheless, detection of snow impurities may be plausible after
intense pollution events or very near pollution sources.
This is one goal of our POLARCAT intense modeling effort
(Section~\ref{sxn:polarcat}).

\csznote{
Greenland is an ideal location for evaluation of SNICAR from remote
sensing platforms.
Most importantly, it is free of the confounding effects of
sub-gridscale vegetation.
Much of the ice sheet enjoys year round sub-freezing temperatures 
where liquid effects are unimportant.
} % csznote

On the other hand, retrieving surface snowpack effective
radius~$\rdsffc$ from operational satellite observations is feasible
and would help identify biases in Arctic $\rdsffc$ predictions.
Remote sensing of snow grain size has been demonstrated with
hyperspectral airborne instruments such as AVIRIS
\cite[][]{PDR03,DoP04}.  
The same principles apply to MODIS and/or MISR radiances, although
these products currently have problems associated with large zenith
angles and topography \cite[][]{ZDT03}. 
If and when the MODIS/MISR high-latitude spectral snow reflectance 
$\rfl(\wvl)$ products reach robust operational status, we will
try to infer~$\rdsffc$ using a radiance ratio technique.
For example, MODIS Channel~5 (1.24\,\um) to Channel 4 or~6 (0.55 and
1.64\,\um, respectively) reflectances
(Figures~\ref{fgr:rfl_spc_rds_ffc}a and~b, respectively).
Researchers will be welcome to use/assimilate our predicted~$\rdsffc$
to attempt to improve MODIS/MISR reflectance retrievals.
In combination with temperature from meteorological analyses,
retrieved~$\rfl$ and/or $\rdsffc$ could be used to evaluate SNICAR's 
surface snow grain size \cite[][]{FlZ06} globally, or, more precisely,
wherever clouds are not contaminating the scene.

AMSR-E retrieves Snow Water Equivalent (SWE) over non-ice surfaces. 
SWE retrievals may provide useful constraints on SNICAR simulations
of continental snowpack.
We will use AMSR-E sea-ice concentration and snow depth over sea-ice
products to evaluate the effect of implementing SNICAR in CICE. 
Current AMSR-E retrieval algorithms \cite[]{MaC98,MaC00} reduce
previous ice concentration biases resulting from surface glaze and 
layering in the snow cover and from thin ice types.
Comparisons of sea-ice extent simulations between AMSR-E and CICE
during and after strong BC years will help us assess climatological BC
impacts on sea-ice.
Daily comparisons of sea-ice snow thickness will help us evaluate
BC impacts from the intense plume we will characterize for the
POLARCAT event study (Section~\ref{sxn:polarcat}).
The potential for our predicted snow grain size distributions to
improve satellite microwave retrievals of snow properties is 
intriguing, though beyond the scope of this proposal.
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{IPY POLARCAT Participation}\label{sxn:polarcat} % Section~\ref{sxn:polarcat}
We will contribute to the IPY ``POLar study using Aircraft, Remote
sensing, surface measurements and modeling of Climate, chemistry,
Aerosols and Transport'' 
(\href{http://zardoz.nilu.no/~andreas/POLARCAT}{POLARCAT}) project
(the attached letter from the IPY program office to POLARCAT PI~Stohl
simply verifies that POLARCAT is an ``official'' IPY to those who
might not be familiar with it).
One of POLARCAT's main themes is the influence of biomass burning and
fossil fuel pollution on the Arctic.
Although many observational aspects of POLARCAT are still pending,
support for regular aerosol concentration and composition measurements
at Summit, Greenland appears to be in place.
A number of
\href{http://zardoz.nilu.no/~andreas/POLARCAT/PAAircraftExp.html#wp3d}{Proposals} 
for aircraft campaigns to track fire plumes from North America across
the Arctic in summer 2008 are pending.
Using modeled/assimilated BC deposition from NCAR collaborator 
and POLARCAT Steering Committee member P.~Rasch (see attached letter
of support), and UCI colleague J.~Randerson, our group will
simulate a boreal fire plume well-characterized during POLARCAT.  
Randerson will constrain emissions will be constrained using GFED 
techniques, Rasch will use CAM in assimilation mode to transport the
plume across the arctic, and our group will characterize atmospheric
and surface radiative forcing by the pollutants and compare to the
in~situ observations.

\csznote{
The field measurements that would most help reconcile remaining
discrepancies between our SNICAR model and spectral reflectance
measurements are: snow accumulation and vertical profiles of
optically-effective grain size, snow density, aerosol concentration,
aerosol optical properties and snowpack temperature.
} % end csznote
Dr.~Tom Painter (NSIDC) studies snow
aging, dust-driven heating of mid-latitude snowpacks, and retrieval of
snowpack reflectance, size distribution and impurities from remote
sensing instruments \cite[e.g.,][]{PDT01,PDR03}. 
Painter has developed a quick method to measure optically effective 
snow grain size in situ \cite[]{PMC07}.
Painter's snow reflectance, particle size, and dust concentration
measurements in the Colorado Rockies have been very helpful to our
snow-aerosol radiative closure experiments.
Vertical profiles of snow grain size would be highly complementary
to the measurements Warren's team will make at selected sites
(snow density profile, spectral reflectance, and impurity
concentration/optical properties) and to the POLARCAT exercise.
If Painter conducts these measurements in the Arctic during IPY,
we will use them for more complete closure experiments for SNICAR
simulations of Arctic snow evolution.  
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{Numerical Experiment Strategy}\label{sxn:xpt}
Our questions (Section~\ref{sxn:obj}) will be addressed in the context 
of pre-industrial, present day, and next century timescales as
appropriate.  
\iftskbrk{\clearpage}{} % Break page after each task
\begin{floatingtable}[r]{ % begin Table~\ref{tbl:mdl}
\begin{tabular}{ >{\raggedright}p{8.0em}<{} llll l }
\hline \rule{0.0ex}{\hlntblhdrskp}%
Scenario &
Source\footnote{BC/OC source options include Type (Fossil Fuel/Biofuel
  and/or biomass burning), Location (Tropics and/or Boreal), and
  Regions (North America, Asia), and prescribed burn seasons (e.g.,
  early/late summer). Dust emissions are global.} & 
Interactions\footnote{Feedback options include Surface
  (post-deposition BC forcing feeds-back to climate), Atmosphere
  (Atmospheric BC forcing feeds-back), and Both.} & 
Climate\footnote{Climate options include Analyses (NCEP/NCAR
  re-analysis meteorology and SSTs), SOM (climatological deep ocean
  with Slab Ocean Model), IPCC (A1B transient ramp to 720\,\ppm\ \COd).} & 
Optics\footnote{Optics/aging options include External (soot externally
  mixed with clouds and snow), Internal (soot internally mixed with
  clouds and snow), and Coated (aged BC has spherical sulfate coating).} & 
GISS\footnote{Checkmark indicates D.~Koch will replicate experiments with
  with GISS model for intercomparison.}
 \\
\hline \rule{0.0ex}{\hlntblntrskp}%
%\multicolumn{6}{c}{\textit{Control}} \\[0.0ex]
Control & Vary & Sfc.$+$Atm. & SOM & Coated & $\checkmark$ \\[0.5ex]
\multicolumn{6}{c}{\textit{Objective~\ref{idx_obj_csn}: Arctic climate sensitivity to timing and location of soot emission}} \\[0.0ex]
Fire location & Vary & Sfc.$+$Atm. & SOM & Coated & \\[0.5ex]
Fire seasonality & Vary & Sfc.$+$Atm. & SOM & Coated & \\[0.5ex]
Forcing/Feedback & Vary & Vary & SOM & Coated & $\checkmark$ \\[0.5ex]
\multicolumn{6}{c}{\textit{Objective~\ref{idx_obj_sea_ice}: Arctic BC impacts on sea-ice}} \\[0.0ex]
Sea-ice feedbacks & All & Sfc.$+$Atm. & Vary & Coated & \\[0.5ex]
Sea-ice asymmetry & Vary & Sfc.$+$Atm. & SOM & Coated & \\[0.5ex]
\multicolumn{6}{c}{POLARCAT Event Simulation} \\[0.0ex]
Control 2007/2008 & All & Sfc.$+$Atm. & Analyses & Vary & \\[0.5ex]
\multicolumn{6}{c}{\textit{Objective~\ref{idx_obj_ghg_aer}: Effective Arctic forcings of GHGs and aerosols}} \\[0.0ex]
\multicolumn{6}{c}{Predictions to 2100} \\[0.0ex]
Equilibrium & All & Sfc.$+$Atm. & SOM & Coated & $\checkmark$ \\[0.5ex]
Transient & Vary & Sfc.$+$Atm. & IPCC/SOM & Coated & $\checkmark$ \\[0.5ex]
\hline
\end{tabular}}
\caption[CCSM/SNICAR Simulations]{\textbf{CCSM/SNICAR Simulations}
\label{tbl:mdl}}
\end{floatingtable} % end tbl:mdl
Natural (i.e., unforced) interannual variability is quite large in
the Arctic climate system \cite[e.g.,][]{BrB982,FWJ99}. 
Boreal fire variability is also quite large \cite[][]{VRG06} and
causes much of the interannual variability in Arctic BC deposition
\cite[][]{FZR07}.    
Detecting and assessing the relatively small (though important) signal
of aerosol-induced Arctic change (Figures~\ref{fgr:rfl_spc_rds_ffc}b
and~\ref{fgr:mlt_Grn}) against the noisy background of natural Arctic
variability will be difficult. 

We will continue to employ an ensemble-based approach to increase the 
signal/noise ratio.
The ensemble comprises multiple identical numerical experiments with
slightly perturbed initial conditions.
To obtain the climate responses presented in this proposal we 
conducted perennial 1997-, 1998-, and 2001-emissions experiments in
separate 15\,yr. simulations.
We used a Student's $\ttt$-test to quantify statistical significance
of Arctic changes between the two ensembles.
Significant ($\cnfstt < 0.05$) changes appear as cross-hatched regions
in Figures~\ref{fgr:rfl_spc_rds_ffc}b and~\ref{fgr:mlt_Grn}. 

We plan numerous numerical experiments to systematically quantify 
aerosol impacts on cryospheric climate sensitivity and surface
hydrology (Table~\ref{tbl:mdl}).
Many of these experiments are also designed to segregate robust from 
model-dependent results.
Our collaborator Dr.~Dorothy Koch (GISS, see attached letter of
support) will replicate the subset of Table~\ref{tbl:mdl} experiments
indicated by checkmarks in the GISS climate models with identical
forcing scenarios to our CCSM experiments.
The purpose of replicating controlled experiments in two GCMs is to
understand model-dependent uncertainties, such as dry vs.~wet
deposition, aerosol direct radiative forcing forcing per unit mass,
and forcing efficacy.
%\cite{KoH05} found that South Asia contributes 20--40\% of Arctic BC.

\csznote{
\begin{floatingfigure}[r]{0.50\hsize}
\centering
\includegraphics[width=0.8\hsize,angle=270]{/home/zender/prp_IGPP06/fgr_sotfrc}
\caption{Difference in summer surface forcing [\wxmS] from black
carbon in snow on sea-ice between a strong boreal fire year (1998) and 
a weak year (2001).}
\label{fgr:frc_cice}
\end{floatingfigure}
} % end csznote

Using the SNICAR snowpack model, \cite{FZR07} show that microphysical
feedbacks (Figure~\ref{fgr:fdb_dgm}) may double snowpack BC forcing
efficacy relative to GISS estimates \cite[][]{HSR05}.
This inter-model disparity is unsettling and highlights the
uncertainties involved. 
In addition to snowpack representation, such inter-model discrepancies
can be due to differences in emissions, meteorology, transport, and
deposition.   
Quantifying the inter-model disparity associated with each process
will help identify and focus optimal targets for future Arctic field 
and modeling studies.

\cite{FZR07} found that even in years of very strong boreal biomass
burning like 1998 (Figure~\ref{fgr:msn_bc}), industrial and biofuel
BC exceed biomass burning as an Arctic BC source, consistent with
\cite{KoH05}.
However, boreal biomass BC appears to be significantly more
efficacious in the Arctic than industrial/biofuel BC \cite[]{FZR07}.
The proximity of boreal forest BB emissions to snow-covered regions
means that a smaller fraction of hydrophobic BC has aged to
hydrophilic BC before deposition to snow.
Boreal forest fires also peak in summer when insolation and potential
snowpack forcing are greatest, rather than winter when industrial and
biofuel BC emissions peak.
Hence inter-model comparison is a question of response as well
as forcing.
Objective~\ref{idx_obj_csn}, quantifying efficacy as a function of 
time and location, is important in this regard as it will show 
which regions and seasons are most vulnerable to BC forcing,
independent of the model.

In Year~3 we will test the suggestion \cite[e.g.,][]{Jac02,Jac04} that 
targeted reductions in soot emissions may achieve
significant mitigation of Arctic climate change.
Once soot effects are satisfactorily evaluated in our integrated
Arctic simulations, we will conduct numerical experiments to assess
the efficacy of plausible changes in BC emissions. 
These experiments will be designed in consultation with Koch and her 
GISS colleagues, and performed in parallel with them.
\iftskbrk{\clearpage}{} % Break page after each task

\section{Project Coordination}\label{sxn:crd}

\subsection{Personnel}\label{sxn:prs}
PI~Zender will coordinate all project activities.
Zender has extensive experience in global-scale aerosol modeling,
ice cloud physics, aerosol optics, and radiative transfer.
He will work with Domin\'{e} at LGGE to improve representation of 
snow specific surface area changes due to surface hoar, diamond dust,
and melt/freeze cycles (Section~\ref{sxn:lgge}).
Zender's work as first author in Years~2 and~3 will utilize these
improvements to elucidate the relative roles of GHGs and absorbing
aerosols in Arctic climate change. 

A post-doc (to be named) will work for two years, participating in the
intercomparison of Arctic climate simulations with collaborator Koch
at GISS, and, with collaborator Rasch, in simulation, analysis, and
evaluation of a boreal fire plume sampled by the POLARCAT team
(Section~\ref{sxn:polarcat}). 
The post-doc will also be encouraged to pursue opportunistic and
original research in Arctic aerosol-snow-climate interactions related
to the project and to his/her expertise. 

Zender will advise an ESS graduate student in Arctic aerosol studies
throughout (and beyond) the project.
The student will be involved in all global modeling activities, though
focused on Objectives~\ref{idx_obj_csn} and~\ref{idx_obj_sea_ice}.
The student will help integrate realistic snow physics into the CICE
sea-ice model, evaluate and improve snow on sea-ice simulations
(Section~\ref{sxn:polarcat}), and participate on global studies
of the efficacy of carbonaceous aerosol mitigation for Arctic climate.
\iftskbrk{\clearpage}{} % Break page after each task

\subsection{Schedule and Milestones}\label{sxn:tm_ln}\label{sxn:scd}
\noindent\textbf{Year~1}. \textit{Goals}: Improve SNICAR predictions
of hoar, melt/freeze, and impurity effects
\begin{enumerate*}
\item Summer 2007: Zender to LGGE/Grenoble to work with F.~Domin\'{e} 
  and colleagues 
\item Fall 2007: Develop theory for hoar and melt/freeze processes in SNICAR
\item Winter 2008: Predict/observe hoar and melt/freeze effects on
  \SSA, and reflectance $\rfl(\wvl)$
\item Spring 2008: Predict/observe impurity effects on \SSA, $\rfl(\wvl)$
\item Spring 2008: Submit manuscript on hoar and melt-freeze \SSA,
  $\rfl(\wvl)$ results 
\item All year: UCI student ``spins up'' on project and prepares
  emissions and Arctic BC concentration datasets for GCM
  intercomparison  
%\item All year: Painter and CU student isolate clear sky MODIS scenes
%  near surface meteorology stations and infer $\rdsffc$ from $\rfl(\wvl)$ 
\end{enumerate*}
\textbf{Year~2}. \textit{Goals}: Represent snow effects on sea-ice,
begin IPY POLARCAT project 
\begin{enumerate*}
\item Summer/Fall 2008: Graduate student visits E.~Hunke at LANL to
  couple SNICAR physics to CICE sea-ice model 
%\item Summer 2008: Painter, Zender, and UCI graduate student to
%  Greenland for two-week snowpack/radiation closure measurements of
%  BC, $\tptsfc$, $\tptgrd$, $\tmsnw$, $\rfl(\wvl)$, and $\rdsffc(\hgt)$. 
%\item Painter: Compare SNICAR predictions for Arctic $\rdsffc$ with
%  MODIS/MISR-inferred $\rfl(\wvl)$, $\rdsffc$ 
\item Fall 2008: Use Clarke/Warren measurements to refine aerosol
  precipitation- and melt-scavenging
\item Fall 2008: Present results from LGGE work at AGU
\item Winter 2009: Discuss sea-ice results with CCSM PCWG
\item Winter/Spring 2009: Examine impact of soot and dust on Arctic
  summer sea-ice extent 
\item Spring 2009: Manuscript on sea-ice results, manuscript on
  influence of snow physics changes BC/dust simulation biases
\item All year: Zender and postdoc perform CCSM transient simulations
  with identical emissions/surface concentrations as D.~Koch and GISS
  colleagues. 
\item Undetermined: Zender to Norway/NILU for POLARCAT team meeting
  to identify Summer 2008 fire event for intensive modeling studies 
\end{enumerate*}
\textbf{Year~3}. \textit{Goals}: Fully coupled IPCC-transient and LAC
mitigation scenarios 
\begin{enumerate*}
\item Summer 2009: Discuss sea-ice simulations at CCSM conference
\item Summer/Fall 2009: Postdoc to NCAR to coordinate POLARCAT
  event simulation with P.~Rasch
\item Fall 2009: Present POLARCAT and GCM intercomparison results at AGU 
\item Winter/Spring 2010: Efficacy of carbonaceous aerosol mitigation
  for Arctic climate 
\item All year: 
  Integrated absorbing aerosol impact on Arctic climate sensitivity 
\item Spring 2010: Manuscripts on POLARCAT event simulation and
  historical and future Arctic simulations
\csznote{
% fxm: put this as innovative new idea in main section not time-line
\item Scale fire emissions from Randerson by ice core data (from
  Saltzman and McConnell) to estimate 1000\,year BC impacts on Greenland
} % csznote
\end{enumerate*}
\textbf{Year~4}. (unfunded wrap-up)
\begin{enumerate*}
\item Fall 2010: Present results of transient IPCC/LAC scenarios at AGU
\item All year: Finish manuscripts
\end{enumerate*}
\iftskbrk{\clearpage}{} % Break page after each task

\section{Results from Prior NSF Funding on Related Projects}\label{sxn:prr}

Zender was PI on 
\href{http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0503148}{ATM-0503148}:
``SGER: Improving CCSM Snow/Ice Radiative and Heating Processes and
Assessing the Importance of the Soot Albedo Effect'', \$26828,
2/1/2005--1/31/2006.
This SGER grant partially funded graduate student Mark Flanner for one
year during which he published one paper \cite[]{FlZ05}, placed one 
manuscript in review \cite[]{FlZ06}, and gave three national meeting 
presentations.  
\cite{FlZ05} shows that resolving the vertical distribution of solar
radiant heating within snowpack remediates significant climatological
biases in the Tibetan Plateau region.
\cite{FlZ06} study snowpack aging and its effect on albedo.
This the first theoretical study to quantify the relative roles of
initial size distribution, vertical temperature gradient, and snow
density in snow albedo evolution (discussed further in
Section~\ref{sxn:snicar}).  
Publications seeded by this grant include \cite{RLF06} and
\cite{FZR07}.   

\csznote{
Zender was PI on 
\href{http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0321380}{ATM-0321380}:
``Acquisition of an Earth System Modeling Facility (ESMF)
for Coupled Climate, Chemistry, and Biogeochemistry Studies''
\$773543, 8/1/2003--7/31/2006. 
The \href{http://www.ess.uci.edu/esmf}{ESMF} is a collaborative
computational resource for UCI's Earth System Science (ESS)
Department students and researchers. 
This includes eight professors, four full-time researchers, and about
a dozen graduate students performing global modeling/analysis for
their dissertations. 
In order to utilize spare cycles when ESS jobs are not running, 
the ESMF provides free (though lower priority) access to
researchers/students from any UCI department.  
A summary of (about two dozen) published and in-press papers which
used and acknowledged the collaborative ESMF scientific computing
facility is maintained 
\href{http://dust.ess.uci.edu/prp/prp_mri/prp_mri_apr_smr.txt}{here}.
} % end csznote

\section{Related Projects, Broader Impacts and Education}\label{sxn:mpc}

\subsection{Related Projects}\label{sxn:clb}
Collaborations with GISS, LANL, LGGE, NCAR, and U.~Washington 
will benefit this project and are endorsed in attached letters of
support.  
We plan to support these and other synergistic projects in at least
the following ways:
\begin{enumerate*}
\item Dr.~Phil Rasch 
  (see attached letter of support and Section~\ref{sxn:ccsm}).
  As originator of the BC/OC aerosol physics in CAM, Rasch is
  interested in incorporating the soot optical properties we are  
  continually improving for SNICAR, back upstream into CAM.
  Rasch's simulations of pollution events during POLARCAT will benefit
  from these optical properties and from the improved snow and sea-ice
  response.
\item Drs.~Elizabeth Hunke
  (see attached letter of support and Section~\ref{sxn:cice})
  and Dr.~Bill Lipscomb, LANL.
  All CICE users will eventually benefit from the improved upper
  boundary condition that SNICAR to the sea-ice.
  Lipscomb, in the same LANL group, is concurrently adapting
  the \href{http://wiki.nesc.ac.uk/read/glimmer-project}{GLIMMER} ice  
  sheet model \cite[]{Pay99} to the CCSM framework.
  LANL would like to use our SNICAR snow-aerosol physics as their ice
  sheet upper boundary condition. 
  Assisting this effort will be relatively straightforward given 
  the similar (CLM-ish) code structure and our close collaboration on 
  the sea-ice.
  This would complete the integrated treatment of clean and dirty snow
  in CCSM, a major milestone for the community.
\item Dr.~Tom Painter (NSIDC) has been measuring snow spectral
  reflectance, snow grain size, and dust concentration to understand
  the the influence of dust on catchment/basin hydrology in the
  Rockies. 
  He is interested in simulating the direct forcing of snowpack
  impurities on reflectance using SNICAR snow aging and reflectance
  physics, coupled to, or instead of, the SNTHERM hydrology.
\csznote{
  Painter and Zender intend to submit a separate proposal to the
  upcoming NSF IPY solicitation for such a field experiment.
  That proposal will be to measure daily spectral surface reflectance
  and snow grain size, density, and temperature profiles at an Arctic
  site during a multi-week period in summer 2008. 
} % csznote
\item Dr.~Jim Randerson (UC~Irvine) is primary developer of the GFED
  burning emissions database (see Section~\ref{sxn:fire}).
  Randerson is PI and Zender is a Co-PI on NSF \label{prj:fire}
  (\href{http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0628637}{ATM-0628637}): ``Collaborative Research: Fire at the Intersection of Global Carbon and Water Cycles'' from 10/1/2006--9/30/2010 (the ``Fire Project'').
  Institutional collaborations led by J.~Foley (U.~Wisconsin) and 
  N.~Mahowald (NCAR) join us to study climate-fire interactions in the
  context of the carbon/nitrogen-cycles and land-use change. 
  The Fire Project will infer historical and construct future fire
  emission datasets to study the interactions of biomass burning emissions 
  with the carbon cycle and tropical interannual variability such as ENSO. 
  The ANS project will use these datasets to study the influence of
  these trends in the Arctic, while the Fire Project will be an early
  beneficiary of improvements to SNICAR and Arctic climate response to
  carbonaceous aerosols developed by this ANS project.
\csznote{
  Two UCI graduate students (M.~Tosca and H.-W. Lin) devoted to the
  Fire Project will develop historical fire forcing datasets and study
  the interactions of tropical BB emissions with the carbon cycle and
  tropical interannual variability such as ENSO.
} % end csznote
\item Dr.~Natalie Mahowald (NCAR) is the NCAR lead on the Fire
  project and is Zender's long-time collaborator on dust studies.
  Mahowald has developed estimates of glaciogenic and anthropogenic
  dust sources which we may use in past (LGM) and future Arctic
  climate scenarios.
  As part of the Fire Project Mahowald and Dr.~Peter Thornton (NCAR)
  and Randerson are implementing a prognostic boreal fire regime in a
  dynamic vegetation and carbon/nitrogen cycling version of the CLM. 
  The atmospheric and cryospheric response to fire will benefit from
  the improvements this ANS project will bring to SNICAR.
\item Mr.~Mark Flanner is currently a graduate student with Zender at
  UC~Irvine and will graduate in Spring 2007. 
  Flanner has been the primary developer of SNICAR. 
  He has committed to a multi-year postdoctoral position at NCAR
  (beginning Summer 2007), funded by the Fire Project, to continue
  exploring BC impacts on climate, including tropical climate.  
  He plans to remain actively involved with SNICAR development and
  thus would benefit from and contribute to the SNICAR improvements
  outlined in this ANS proposal. 
\item Drs.~Steve Warren (U.~Washington, see attached letter of support  
  and Section~\ref{sxn:insitu}), Tom Grenfell and Tony Clarke
  (U.~Hawaii). 
  Warren's team may benefit from using our global snow, BC, and dust
  predictions and hindcasts to help their search for optimal sampling 
  locations. 
\csznote{
\item Dr.~Eric Saltzman (UC~Irvine) measures trace gas and aerosol 
  concentrations in ice cores \cite[e.g.,][]{SAD04} and Co-PIs a 
  proposed ARO project ``High-Resolution, Biomass-Burning-Specific
  Tracers in Greenland Ice Cores over the Past 1000~Years''.
  In conjunction with Randerson's fire emission database, our project
  provides a method to quantify the impact of Saltzman's proxy
  measurements of biomass burning aerosol variability in Greenland
  over the last 1000\,yr. 
} % end csznote
\end{enumerate*}

\subsection{Improved Community Modeling Capabilities}\label{sxn:mdl_mpr}
Snow pervades the Arctic, and improved snowpack models can and
probably will improve understanding of Arctic hydrology.
Zender has provided many useful research models to various communities
including the Column Radiation Model 
(\href{http://www.cgd.ucar.edu/cms/crm}{CRM}),
the Dust Entrainment and Deposition Model
(\href{http://dust.ess.uci.edu/dead}{DEAD}),
and the netCDF Operators (\href{http://nco.sf.net}{NCO}).
SNICAR is and will be freely available for use in land, atmosphere,
and sea-ice components (CLM, CAM, and CICE, respectively) of the
CCSM.
All the snow model developments will translate directly to the new ice
sheet model being built at LANL and intended for use in CCSM global
climate experiments. 
Hence extending and improving SNICAR's physics will contribute to
Arctic research areas including glacier mass balance (through
realistic upper boundary radiation and melt conditions),  
basin and catchment hydrology (improved representation of snowpack
sublimation vs.\ internal melt and surface percolation), 
physical impact of algae on snow,
paleoclimate sensitivity (through improved accuracy of Arctic
responsiveness to orbital and aerosol forcing),  
and snow chemistry improved representation of snowpack SSA
\cite[]{DoS02}.  
% DoS02 review air-snow chemistry

\subsection{Education}\label{sxn:edc}
This project trains one graduate student in Arctic aerosol-climate
interactions.
UC Irvine is a US Department of Education Minority Serving
Institutions with large pools of under-represented minorities (URMs)
potentially interested in pursuing undergraduate research projects. 
The UCI ESS department where Zender teaches has three programs which
pipeline URMs to ESS research opportunities: (1) CAMP (Campus Alliance 
for Minority Participation) in Science, Engineering and Math, 
(2) an NSF \href{http://www.ess.uci.edu/reu}{REU in ESS} (2006--2009,
PI J.~K. Moore of ESS), and (3) a NASA Education Grant (2006--2009, PI
J.~Randerson of ESS). 
With these resources Zender will open a year-round undergraduate
research position in his group at no additional cost to NSF. 
The student will assist inverting snowpack spectral measurements for 
aerosol optical properties and mixing state given measured aerosol
concentrations. 

Moreover, PI~Zender helps train Orange County K--12 teachers in Earth
Science curricula. 
An NSF Math Science Partnership project called
\href{http://focus.mspnet.org}{FOCUS}  
(Faculty Outreach Collaborations Uniting Scientists, Students and
Schools)
brings the teachers to UCI.
Zender will incorporate Arctic climate change materials into 
\href{http://dust.ess.uci.edu/smn/smn_sun_focus_200508.pdf}{his FOCUS seminars}.
Zender will also incorporate this Arctic research into his
\href{http://dust.ess.uci.edu/smn/smn_arc_mlt_olli_200610.pdf}{seminars}
to students of the Osher Lifelong Learning Institute 
(\href{http://unex.uci.edu/community/olli/index.asp?}{OLLI}).
\newpage

\section*{References}\label{sxn:rfr} % \section* does not number section
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\newpage

\subsection{Budget Justification}\label{sxn:bdg_jst}
\setcounter{page}{1}
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\subsubsection{Salaries and Wages}
One month of summer support for three years is requested for
Prof.\ C.~Zender, the PI, who will have primary responsibility for the
proposed research.  Zender requests his sabbatical differential salary
in Year~1 (\$25,542), when he will be in residence at LGGE/Grenoble
performing controlled snow studies with collaborator F.~Domin\'{e}.
In Year~2 the project will focus more on solar energy distribution and
snow aging evaluation in the Arctic sea-ice regime.
In Year~3 the project will elucidate the relative roles of GHGs and
absorbing aerosols in Arctic climate change.

A postdoctoral scholar is requested in Years~2 and~3.  
The postdoc will perform original research applying our snow aging and 
aerosol semi-direct forcing techniques to the IPY POLARCAT field
exercise (in collaboration with P.~Rasch) and climate simulations 
that quantify the efficacy of Arctic aerosol forcing in various IPCC 
scenarios (in collaboration with D.~Koch). 
The PI thinks that the proposed CCSM-GISS inter-model comparison is
better suited to a post-doc than a graduate student because GCM
intercomparison is best done by someone already comfortable and
familiar with the inner workings of at least one global model. 

To be Named---Graduate Student Researcher~III.  Funds are requested to
support one non-resident graduate student each year of the project.
The graduate student support is requested at 50\% for 9~months during
the academic year and 100\% for 3~months during the summer. 
The student will be involved in most global modeling activities:
integrating realistic snow physics into the CICE sea-ice model, 
evaluate and improve snow/sea-ice simulations (in collaboration with
E.~Hunke), and participating in global studies of the efficacy of
carbonaceous aerosol mitigation for Arctic climate. 

All salaries and wages were estimated using UCI's academic and staff
salary scales.  A 2\% cost-of-living increase was applied each year of
this proposal as well as a 5\% merit, where applicable. 

\subsubsection{Employee Benefits}
Fringe Benefits were estimated using the composite rates agreed upon
by the University of California Office of the President and the DHHS
Audit Agency, the Cognizant Audit Agency for the University of
California.  Benefit rates used in this proposal are:\\
Faculty --- academic year --- 17\%\\
Faculty --- summer --- 12.7\%\\
Postdoc --- 17\%\\
Student employees --- summer --- 3\%\\
Student employees --- academic year --- 1.3\%\\

Fees and tuition are requested for one nonresident student for the
duration of the project. University of California policy requires
award payment of fees for any student with more than 25\% support from
a grant.  In the first year, \$26,951 is requested, \$29,511 in the
second year, and \$32,338 in the third year.    Fees and tuition are
excluded from indirect cost assessment. 

\subsubsection{Equipment}
Equipment funds are requested for two Linux scientific workstations
(dual or quad CPU, 4\,GB RAM) at \$5,000 each. 
One in year one (for the graduate student) and one in year two (for the postdoc). 
These workstations will include adequate RAID'ed disk space (2--4\,TB) for the
researchers to store and analyze CCSM model output and satellite
MODIS, MISR, and AMSR-E datasets. 

\subsubsection{Travel}
Domestic:  Round-trip travel at \$2000 per trip is requested for the
PI and graduate student to travel to national meetings (primarily AGU)
to present results in Years 2 and~3.  Each trip includes round-trip
travel from Irvine to San Francisco, one-week hotel and per diem.
Round-trip travel at \$2,000 per trip is requested for the postdoc
(Year~2) and PI (Year~3) to travel to NASA GISS in New York City to
intercompare models with collaborator D. Koch.  This includes
round-trip, lodging and per diem for one week.  Round-trip travel is
requested for the graduate student and PI to travel to Los Alamos NM
to work on sea-ice modeling with LANL collaborator E.~Hunke. One month
housing is requested for the graduate student who will work closely
with Hunke. One week lodging is requested for the PI. Travel expenses
for the graduate student are estimated at \$3,500 (for one month) and
\$1,000 (for one week) for the PI.  These trips include estimated
conference registration, abstract submission fees, RT airfare,
lodging, meals and ground transportation.  Travel estimates are based
on historical usage. 

International:  One round-trip at \$1,500 is requested for the PI to
travel to Grenoble, France in Year~1 to collaborate with F.~Domine
while on sabbatical. This trip includes only transportation. One
round-trip at \$3,000 is requested for the PI to travel to Norway in
Year~2 to participate in IPY POLARCAT team meeting activities and to
present results. This trip includes roundtrip travel from Irvine to
Oslo, one-week hotel and per diem. These trips include estimated
conference registration, abstract submission fees, RT airfare,
lodging, meals and ground transportation. Travel estimates are based
on historical usage. 

\subsubsection{Other Direct Costs}
Charges for journals, photocopying, long distance phone, FAX and
postage charges pursuant to this project are requested.  Included in
these expenses are long-distance charges for usage directly related to
the project, such as communication with colleagues, journals, and
vendors.    Photocopying of research materials including publications
and results of this sponsored research project are requested as well
as mail and shipping for materials related to this project. These
costs are estimated at \$500 per year.  Support is requested for
publication costs (\$2,000 in Year~1, \$4,000 in Year~2 and \$6,000 in 
Year~3) pursuant to this project, which include utilization of
expensive color figures.  Costs were estimated according to historical 
usage. 

\subsubsection{Indirect Costs}
Facilities and Administrative costs were estimated in accordance with
UCI's approved indirect cost rate agreement.  The indirect cost rate
of 52.5\% of MTDC effective 7/1/05 was based upon the nature and
location of the work proposed.  Graduate student fees and tuition and
equipment are excluded from indirect cost assessment.  UCI's indirect
cost rate agreement was approved by DHHS, the Federal Cognizant Audit
Agency for UCI on 12/5/01. 
\newpage

\section{Facilities, Equipment, and Other Resources}
\subsection{Computational Resources}
\setcounter{page}{1}
\thispagestyle{empty}
The computational activities in this project will take place at one
of three computing facilities based on the simulation scale.
PI~Zender directs the UCI Earth System Modeling Facility 
(\href{http://www.ess.uci.edu/esmf}{ESMF}),
an NSF-supported MRI facility.
The ESMF flagship machine is an 88-CPU Power4+ IBM supercomputer with 
192\,GB RAM and 16\,TB of RAID storage.
In summer 2006 ESMF acquired a new Beowulf cluster (named IPCC)
comprising twenty-seven two-way dual core Opteron nodes (108~CPUs) and
5\,TB of RAID storage. 
This ANS proposal fits squarely within the ESMF mission, and the ESMF 
will host the initial modeling development and shorter simulations.

Coupling, testing, and shorter evaluations of SNICAR with CICE will
occur at UCI.
Longer sea-ice simulations with collaborator E.~Hunke will be
performed at LANL or NCAR, which both support the CCSM on
supercomputer facilities designed for long, ``production''
simulations. 
We will request supplementary time at NCAR for the ensemble of
equilibrium and transient simulations of the fully coupled CCSM/SNICAR
code outlined in Table~\ref{tbl:mdl}. 
This will be done under the auspices of the Polar Climate Working
Group, which is co-chaired by collaborator E.~Hunke.
\newpage

\section{Acronyms and Abbreviations}\label{sxn:abb}
\setcounter{page}{1}
\thispagestyle{empty}
%\begin{longtable}{ >{\raggedright}p{7.0em}<{} >{\raggedright}p{8.0em}<{} }
\begin{longtable}{ r >{\raggedright}p{25.0em}<{} l }
& \kill % NB: longtable requires caption as table entry
\caption[Acronyms and Abbreviations]{\textbf{Acronyms and Abbreviations}%
\label{tbl:abb}} \\
\hline\hline \rule{0.0ex}{\hlntblhdrskp}% 
Abbreviation & Description & \\[0.0ex]
\hline \rule{0.0ex}{\hlntblntrskp}%
\endfirsthead % Lines between and \endfirsthead appear at top of table
\caption[]{(continued)} \\ % Set label for following pages
Abbreviation & Description & \\[0.0ex]
\hline \rule{0.0ex}{\hlntblntrskp}%
\endhead % Previous block appears at top of every page
\endlastfoot % Previous block appears at end of table
AGU & American Geophysical Union (meets in San Francisco in Fall) & \\
AMSR-E & Advanced Microwave Scanning Radiometer (satellite instrument) & \\
ANS & Arctic Natural Sciences & \\
AR4 & Fourth Assessment Report & \\
ARF & Aerosol Radiative Forcing & \\
ATSR & Along Track Scanning Radiometer and Microwave Sounder & \\
AVIRIS & Airborne Visible/Infrared Imaging Spectrometer & \\
AWS & Automated Weather Station & \\
BB & Biomass Burning & \\
BC & Black Carbon (light-absorbing component of carbonaceous aerosol) & \\
BF & Biofuel & \\
BRDF & Bi-directional Reflectance Distribution Function & \\
CAM & Community Atmosphere Model (atmosphere component of CCSM) & \\
CCSM & Community Climate System Model & \\
CICE & Los Alamos sea-ice model (sea-ice component of CCSM) & \\
CLM & Community Land Model (land component of CCSM) & \\
CRM & Column Radiation Model & \\
DEAD & Dust Entrainment And Deposition Model & \\
EMA & Effective Medium Approximation & \\
ESM & Earth System Model & \\
ESMF & Earth System Modeling Facility & \\
ESS & Earth System Science (Department) & \\
FF & Fossil Fuel & \\
FOCUS & Faculty Outreach Collaborations Uniting Scientists, Students and Schools & \\
GCM & General Circulation Model & \\
GFED & Global Fire Emissions Database & \\
GHG & Greenhouse Gas & \\
GISS & Goddard Institute for Space Studies & \\
GLIDE & General Land Ice Dynamic Elements (core of GLIMMER) & \\
GLIMMER & Ice Sheet Model of Payne et~al. & \\
GSFC & Goddard Space Flight Center & \\
IPCC & Intergovernmental Panel on Climate Change & \\
IPY & International Polar Year & \\
LAC & Light Absorbing Carbon (light-absorbing component of carbonaceous aerosol) & \\
LANL & Los Alamos National Laboratory & \\
LGGE & Laboratoire de Glaciologie G\'{e}ophysique de l'Environnement (Grenoble, France) & \\
LGM & Last Glacial Maximum & \\
MISR &  Multi-angle Imaging Spectro-Radiometer (satellite instrument) & \\
MODIS &  Moderate Resolution Imaging Spectroradiometer (satellite instrument) & \\
NASA & National Aeronautic and Space Administration & \\
NCAR & National Center for Atmospheric Research (Boulder, Colorado) & \\
NCO & netCDF Operators & \\
NIC & National Ice Center & \\
NILU & Norwegian Institute for Air Research (Kjeller, Norway) & \\
NIR & Near InfraRed & \\
NSIDC & National Snow and Ice Data Center & \\
OC & Organic Carbon & \\
OLLI & Osher Lifelong Learning Institute & \\
OPAC & Optical Properties of Aerosols and Clouds (\cite{HKS98}) & \\
PCWG & (CCSM) Polar Climate Working Group & \\
PI & Principle Investigator & \\
POLARCAT & POLar study using Aircraft, Remote sensing, surface measurements and modeling of Climate, chemistry, Aerosols and Transport (IPY project organized by Andreas Stohl of NILU) & \\
RT & Radiative Transfer & \\
SEI & Science and Engineering Informatics & \\
SEM & Scanning Electron Microscopy & \\
SGER & Small Grant for Exploratory Research & \\
SHEBA & Surface Heat Budget of the Arctic (field campaign on Arctic sea-ice) & \\
SNICAR & SNow, ICe, and Aerosol Radiative model & \\
SNTHERM & Snow Melt model & \\
SOM & Slab Ocean Model & \\
SSA & Specific Surface Area & \\
SWE & Snow Water Equivalent & \\
TG & Temperature Gradient & \\
UCI & University of California, Irvine & \\
\end{longtable} % end tbl:abb
\newpage

\section{Project-Wide Combined Collaborator and Advisor List}\label{sxn:prs_lst} 
\setcounter{page}{1}
\thispagestyle{empty}
% Currently includes: Zender
All Personnel Associated with Proposal, Collaborators and
Co-Editors of Project Senior Personnel, their Post-docs, and their
Thesis Advisors:
\begin{enumerate*}
\item[] Ammann, C.~A. (NCAR) 
\item[] Bian,~H. (NASA/UMBC) 
\item[] Bonan, G.~B. (NCAR) 
\item[] Busacca,~A. (WSU)
\item[] Cakmur,~R. (NASA GISS) 
\item[] Colarco,~P. (GSFC)
\item[] Collins, W.~D. (NCAR) 
\item[] Cooper, W.~A. (NCAR)
\item[] Famiglietti,~J. (UCI) 
\item[] Gaylord,~D. (WSU)
\item[] Grini,~A. (U.~Oslo)
\item[] Jenks,~S. (UCI) 
\item[] Khalsa, S.~J.~S. (NSIDC)
\item[] Kiehl, J.~T. (NCAR) 
\item[] Kuester,~F. (UCI) 
\item[] Levin,~Z. (TAU, Israel) 
\item[] Mahowald, N.~M. (NCAR) 
\item[] Miller,~R. (NASA GISS) 
\item[] Moore, J.~K. (UCI) 
\item[] Okin,~G. (U.~Virginia) 
\item[] Painter,~T. (NSIDC) 
\item[] Pajarola,~R. (UCI) 
\item[] Papadopoulos,~P. (UCI)
\item[] Rasch, P.~J. (NCAR)
\item[] Tegen,~I. (IfT, Germany) 
\item[] Thomas, G.~T. (CU) 
\item[] Torres,~O. (NASA GSFC)
\item[] Valero, F.~P.~J. (Scripps) 
\item[] Yu,~S. (Duke) 
 \end{enumerate*}
\newpage

List is Alphabetical by Surname.
\begin{enumerate*}
\item[] Collaborators of Zender:
\begin{enumerate*}
\item[] Ammann, C.~A. (NCAR) 
\item[] Bian,~H. (NASA/UMBC) 
\item[] Bonan, G.~B. (NCAR) 
\item[] Busacca,~A. (WSU)
\item[] Cakmur,~R. (NASA GISS) 
\item[] Colarco,~P. (GSFC)
\item[] Collins, W.~D. (NCAR) 
\item[] Cooper, W.~A. (NCAR)
\item[] Famiglietti,~J. (UCI) 
\item[] Gaylord,~D. (WSU)
\item[] Grini,~A. (U.~Oslo)
\item[] Jenks,~S. (UCI) 
\item[] Khalsa, S.~J.~S. (NSIDC)
\item[] Kiehl, J.~T. (NCAR) 
\item[] Kuester,~F. (UCI) 
\item[] Levin,~Z. (TAU, Israel) 
\item[] Mahowald, N.~M. (NCAR) 
\item[] Miller,~R. (NASA GISS) 
\item[] Moore, J.~K. (UCI) 
\item[] Okin,~G. (U.~Virginia) 
\item[] Painter,~T. (NSIDC) 
\item[] Pajarola,~R. (UCI) 
\item[] Papadopoulos,~P. (UCI)
\item[] Rasch, P.~J. (NCAR)
\item[] Tegen,~I. (IfT, Germany) 
\item[] Thomas, G.~T. (CU) 
\item[] Torres,~O. (NASA GSFC)
\item[] Valero, F.~P.~J. (Scripps) 
\item[] Yu,~S. (Duke) 
  \end{enumerate*}
\item[] Collaborators of Co-PI Dr.~Who:
\begin{enumerate*}
\item Hi
\end{enumerate*}
\end{enumerate*}
\newpage

\subsection{Supplementary Documents}\label{sxn:spl_doc}
\setcounter{page}{1}
\thispagestyle{empty}
\begin{enumerate}
\item \${DATA}/prp/prp\_ans/prp\_ans\_abb.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_clb.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_domine.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_hunke.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_koch.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_rasch.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_warren.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_polarcat.pdf
\item \${DATA}/prp/prp\_ans/prp\_ans\_ltr\_polarcat.pdf
\end{enumerate}

\clearpage

\csznote{ % E-mail to collaborators
% Letter sent to Liz Ford 20061130
Hi Liz,

I am submitting a single PI proposal to the 2006 NSF Arctic Research 
Opportunities (ARO) announcement, NSF 06-603: 
``Integrating Snow Processes to Improve Understanding and Prediction of
Arctic Climate Change''

The one-page summary is attached.
Please draft me a three year budget 7/1/07-6/30/10 that includes: 

1. 100% sabbatical differential for year 1
2. 1 month summer salary years 1-3
3. 1 international graduate student years 1-3
4. International travel to Grenoble, France in year 1, airfare only
5. Domestic travel to AGU for me and grad student years 2 and 3
6. International travel for me to Oslo, Norway in year 2 one week expeses
7. 1 month visit for grad student to LANL year 2
8. 1 week visit for me to LANL year 2
9. 2 Linux scientific workstations at $5k each
10. Publication expenses years 1/2/3 = $2000/4000/4000

Thanks,
Charlie

% Letter sent to Liz Ford 20061202
Hi Liz,

Please increase the draft budget of my NSF ANS proposal by adding 
support for a postdoc in years 2 and 3. 

P.S. The title has changed to 

Snow Process Studies and Modeling to Improve Arctic Climate Prediction

and a better one page summary has been uploaded.

Thanks,
Charlie

% Letter sent to Florent Domine 20061130
Hello Florent,

I have been (re-)writing an NSF IPY proposal due Friday 12/8.
This is one of two proposals I am writing which would fund my 
sabbatical stay at LGGE. I hope you are still interested in
collaborating.

Attached is the one page proposal summary and the schedule. 
The full proposal, a draft that improves daily, is online at 

http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf

I have not finished writing more details on the first year when I
would be at LGGE. I plan to do this tomorrow and I want to give
you as much advance notice as possible. I plan to describe three
experiments (two that we have already discussed), and I wanted to 
double-check with you on whether this is realistic:
1. Fall 2007: Modeling/measurement of SSA changes from surface hoar 
2. Winter 2008: Modeling/measurement of SSA changes melt/freeze cycles
3. Spring 2008: Modeling/measurement of impurity effects on snow

A letter of support from you would be very helpful because I intend
to collaborate with your group at LGGE in Year 1 on projects to
improve our models, and the proposal explicitly mentions this. 
If you choose to provide a letter of support, it would be most helpful  
to receive a PDF on your letterhead, or an e-mail, by Thursday 12/7. 

Best Regards,
Charlie

Hi Florent,

Attached please find a draft one page summary of Snow SSA
measurements. I welcome your comments. You'll note that I 
left out the fresh snow SSA measurements to help parameterize
initial snow SSA as a function of atmospheric conditions.
I can add that in but I thought that the experiements mentioned 
were already more than enough for one year. 
This proposal has to make the case that it is solving Arctic
problems so there is text on "mimicking" Arctic conditions
once sample are in the lab. Is it possible to do what I wrote?

I am excited by the potential to do controlled impurity studies.
However, is "controlled"  an exaggeration? Is it possible to
somehow distribute known concentrations of impuritities into
snow? Or must one just measure what one finds in the field?

And the melt/freeze experiments---I think there is a crucial
gap in our knowledge here but again, I'm not sure whether your
methane technique will work when liquid is present. Please
clarify if I should change the description from melt/freeze
to warm/freeze, or drop it entirely.

Let me know what you think. Will you be able to send me a 
PDF letter of support sometime Thursday?

Thanks,
Charlie

% Letter sent to Elizabeth Hunke 20061130
Hi Elizabeth,

I am submitting a revised NSF ANS proposal due 12/8.
Similar to our previous proposals, it requests funding for a graduate
student who will work to improve snow physics in CICE sea-ice.
The proposal describes the rationale of porting SNICAR to CICE, and
allocates funds for the student to work at LANL for one-month with 
your guidance (and a one-week visit by me). I apologize for not having
called you earlier to discuss this project. Just say "No!" and
disregard the rest of this message if you do not wish to participate.
I understand that plans change and new opportunities arise.

Good. You're still reading :) Attached is a one page summary, the
portion that most involves you, and the schedule.  
The full proposal, a moving target that improves daily, is online at 

http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf

A letter of support from you would be very helpful because the
proposal explicitly mentions the sea-ice studies numerous times. 
If you choose to provide a letter of support, it would be most helpful  
to receive a PDF on your letterhead, or an e-mail, by Thursday 12/7. 
Your support letter from last year would be a fine template because,
from your point of view, not much has changed. A UCI student would 
work remotely to spin up on the project and then show up at LANL for
a month or so when ready to extend CICE with SNICAR. 

The project involves other elements which are more or less independent
of the CICE component. These include: my sabbatical at LGGE/Grenoble
to work on hoar, diamond dust, and melt freeze improvements to SNICAR,
intercomparison with GISS GCM simulations by Koch et al., continuing
to work with Flanner, Rasch, and Randerson on the physics, transport,
and fire components, and performing IPCC-ish future simulations.

Best Regards,
Charlie

% Letter sent to Dorothy Koch 20061130
Hi Dorothy,

Great! I'm glad you've elected to request a postdoc to work on this.
It will be hard to lure Mark to GISS---though it never hurts to try.
He's received one attractive postdoc offer already.

My letter of support is attached. Let me know if you want changes.
Your text might clarify that Flanner and Zender (2006) describe the
SNICAR model, whereas Flanner et al. (2006, submitted) describe its
global results driven by BC aerosol. 

Attached is a one page summary of my NSF ANS proposal, and the portion  
that most involves you. A letter of support from you would be very
helpful. Mentioning (if true) that you believe SNICAR development will
benefit the Arctic modeling community would be helpful.
If you choose to provide a letter of support, it would be most helpful 
to receive a PDF on your letterhead, or an e-mail, by Thursday 12/7. 

Good luck!
Charlie

% Letter sent to Tom Painter 20061130:
Hi Tom,

As you know I am (re-)writing an NSF Arctic proposal now called "Snow 
Process Studies and Modeling to Improve Arctic Climate Prediction".  
Given the feedback from the program manager, and knowing what
Warren is funded for, I felt that your field measurements would
be hard for NSF to support in this proposal.

The proposal would fund a grad student, and a two year postdoc
to continue studying dirty snow, both BC and dust, and to move to
the next level of feedbacks by including feedbacks with sea-ice.
The proposal will also fund new snow process studies in Florent
Domine's lab at LGGE/Grenoble where I hope to spend my sabbatical.
The results would be integrated into an intense modeling study of
a POLARCAT-characterized plume, and into IPCC-style GCM simulations.

I would very much like to collaborate with you on solar radiative
budget and snowpack evolution experiments anywhere. 
However, I think it would be best if you PI'd such a proposal.
I wrote, and correct me if I'm wrong or should not mention this,
that you have pending proposals to measure spectral reflectance
and grain size in the Arctic during IPY, and that we would find
your data valuable for closure on snow evolution experiments.
I would like to verify that it this OK with you.

Attached is the one page proposal summary, the POLARCAT section
(where the stuff most relevant to you is), and the schedule. 
The full proposal, a bit of a moving target, is online at 

http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf

Would you consider writing a short letter of support?
If yes, it would be most helpful to receive a PDF on your letterhead,
or an e-mail, by Thursday 12/7.

Thanks,
Charlie

P.S. Sorry for the lateness of this, and for continually missing
     calls. Hope to see you in S.F.!

% Letter sent to Phil Rasch 20061130:
Hi Phil,

We are (re-)writing an NSF Arctic proposal called "Snow Process
Studies and Modeling to Improve Arctic Climate Prediction".  
The proposal would fund a grad student, and a two year postdoc
to continue studying dirty snow, both BC and dust, and to move to
the next level of feedbacks by including feedbacks with sea-ice.
We will work with Elizabeth Hunke on coupling SNICAR to the sea-ice.
And possibly with Briegleb's sea-ice physics if that is ready.
The proposal will also fund new snow process studies in Florent
Domine's lab at LGGE/Grenoble where I hope to spend my sabbatical.
The results would be integrated into an intense modeling study of
a POLARCAT-characterized plume, and into IPCC-style GCM simulations.

We would be very interested in collaborating with you on a boreal fire
plume event simulation for POLARCAT.  
With Randerson's fire emissions, your transport, and our radiation
and snow, we could do an integrated end-to-end exercise.
What do you think? May I mention this in the proposal?

This proposal will also rely heavily on continued use of your BC
aerosol model in CAM, with the holiday trimmings that we have added.
I am verifying that we can rely on you for continued guidance on
the BC/OC component, and that I can mention this too.

Attached is the one page proposal summary, the POLARCAT section
(that most involves you), and the schedule. 
The full proposal, a bit of a moving target, is online at 

http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf

Would you consider writing a short letter of support?
If yes, it would be most helpful to receive a PDF on your letterhead,
or an e-mail, by Thursday 12/7.

Thanks,
Charlie

P.S. Sorry for the lateness. Hope to see you in S.F. 

% Letter sent to Steve Warren 20061130
Dear Steve,

Attached is a one page summary of my NSF ANS proposal,
the portion that most involves you, and the schedule.
The full proposal, in flux and improving daily, is online at 

http://dust.ess.uci.edu/prp/prp_ans/prp_ans.pdf

A letter of support from you would be very helpful because the data
your and Tony Clarke's groups collecting are crucial to evaluating
and improving our models, and the proposal explicitly mentions this.
Numerous times :)
If you choose to provide a letter of support, it would be most helpful 
to receive a PDF on your letterhead, or an e-mail, by Thursday 12/7. 

Your support letter from last year would be a fine template.
Briefly, I plan to adopt a graduate student who will pursue a PhD in
aerosol-cryosphere-climate interactions. In year 1, I'll (hopefully)
be with Florent Domine et al. (including Fily) at LGGE in Grenoble.
We'll collaborate on SSA modeling and measurements in lab environments 
relevant to Arctic snowpack. We'll try to improve SNICAR by explicitly
representing SSA of non-precipitation snowpack changes especially
surface hoar and possibly diamond dust. Also hope to try some
melt/freeze experiments and some controlled impurity experiments.
In Year 2 the graduate student has ``spun up'' and commences studies
with impurities in snow on sea-ice, in collaboration with Hunke/LANL.
In Year 3 we'll hindcast the most significant biomass burning plume
characterized during IPY, and apply what we have learned from the
microphysics and sea-ice work to integrated Arctic scenarios.

Thanks!
Charlie
} % end csznote

\csznote{ % E-mail from Steve Warren 20061110
Hi Charlie.

I enjoyed our phone conversation today.

1. Below is the response I wrote last March to Marco Tedesco, who had
proposed satellite detection of the effect of BC on snow albedo. 

2.  You can fetch our paper on spectral BRDF (Hudson et al 2006) from
my website http://www.atmos.washington.edu/~sgw/s_warren_pub.html.
This is the paper that shows that wavelengths with the same albedo
have the same BRDF (compare Figures 5 and 7). 

I look forward to meeting with you at AGU.

Best regards,
- Steve

> Date: Wed, 22 Mar 2006 18:41:39 -0800
> To: mtedesco@umbc.edu
> From: Stephen Warren <sgw@atmos.washington.edu>
> Subject: Re:  Snow impurities from satellite
> Cc: James Hansen <jhansen@giss.nasa.gov>,Tom Grenfell
<tcg@atmos.washington.edu>, Armond Cohen <armond@catf.us>, Ellen Baum
<ebaum@catf.us>,yoram.j.kaufman@nasa.gov, Warren Wiscombe
<Warren.J.Wiscombe@nasa.gov>,dorothy.k.hall@nasa.gov 
>
> Dear Dr. Tedesco,
>
> Thanks for sending me your outline for a proposal.  I think that
satellite observations will not be useful to quantify soot in Arctic
snow, for the following reasons. 
>
> 1.  Satellites still have difficulty detecting clouds over snow, so
we may not know whether we're looking at snow or clouds-over-snow.
Thin near-surface layers of atmospheric ice crystals ("diamond-dust")
are common in the Arctic. 
>
> 2.  If we can be sure we are looking at a cloud-free pixel, then as
you indicate we would choose two channels, one in the near-infrared to
get the snow grain size, and one in the visible to get the soot
(because the albedo-reduction by soot depends on the snow grain size).
Actually we would need two channels in the near-infrared, and would
use their ratio to get grain size, because what the satellite measures
is not albedo but rather radiance into a particular direction.  MODIS
does have enough channels.  However, the anisotropic reflectance
factor (ARF) varies with wavelength, and this variation with
wavelength itself depends on grain size.  The presence of soot in the
snow will also alter its visible ARF (relatively more
forward-scattering, less scattering to zenith), so an iterative
procedure would be needed. 
>
> 3.   The ARF is very much affected by small-scale surface roughness
such as ripples, sastrugi, and suncups.  On sea ice there are also
pressure-ridges, which are much larger.  The height and direction of
sastrugi are altered after each strong windstorm, and the
height-to-width ratios are unpredictable.  The effects of sastrugi on
ARF are different at the different wavelengths, because they depend on
the ratio of sastrugi width to flux-penetration depth (which varies
with wavelength).  When a thin ground-fog (or diamond-dust layer)
covers the snow and thus partially hides the roughness, our
measurements show that the forward peak is enhanced and the nadir view
is darker, even though the albedo is probably unchanged or slightly
higher.  This darkening at nadir could be mistaken for
soot-contamination. 
>
> 4.   Soot can be mimicked.
> (a) Sooty snow has the same spectral signature as thin snow:  both
soot and thinness reduce albedo in the visible but not in the
near-infrared.  So we can't get the soot content from space unless we
know independently the snow thickness. 
> (b) If there is any vegetation in the satellite pixel, this will
cause additional difficulty.  Snow on the tundra is often thin enough
that grass is sticking up through it. 
> (c) In the Arctic Ocean, sub-grid-scale leads will cause a similar
difficulty. So the method appears not to be useful for the forest, the
tundra, and the Arctic Ocean; its use would probably be limited to
flat areas of the Greenland Ice Sheet. 
>
> 5.  MODIS will probably not be able to distinguish between (a) soot
in the snow and (b) soot in the atmosphere above the snow ("Arctic
haze").  Both will give similar spectral signatures when viewed from
above, but their climatic consequences are different:  soot in the
atmosphere shields the surface from sunlight, stabilizes the
atmospheric temperature profile, etc., as shown in the publications
about Arctic haze and "nuclear winter". 
>
> 6.  As Jim Hansen pointed out, significant climatic effects can
>result from changing snow albedo by only 1\%.  If the directional
>radiance measured by MODIS is 1\% lower than your predicted
directional radiance for clean snow of some specified roughness, will
you really be sure that soot is responsible? 
>
> Sincerely,
> - Stephen Warren
>
>
> At 02:53 PM 3/14/2006, mtedesco@umbc.edu wrote:
>
>> I have been contacting already colleagues here at Goddard for receiving
>> some support. So far, Yoram Kaufman and Warren Wiscombe have expressed
>> their interest in the idea and they could provide letters of support to
>> the proposal. Our estimeed colleagues in Europe (Kokhanovsky and Zege)
>> agreed about being unfunded collaborators on the proposal to support the
>> theoretical background of the study. Also, the members of the Goddard Snow
>> Team (Ed Kim, Dorothy Hall and Jim Foster) will support the proposal with
>> a letter to NASA. I wrote yesterday to Jim Hansen and I have been talking
>> to his assistant for a meeting. I think he might be interested in the
>> study and I am waiting for his reply.
>>
>> >>
>> >>We will make use of MODIS observations to derive grain size and soot
>> >>concentration by means of a recently developed snow optical model based
>> >> on
>> >>the representation of snow grains as fractal particles. Grain size values
>> >>will be extracted from MODIS reflectance collected at near-infrared (e.g.
>> >>1245 nm). Soot concentration will be then derived from the reflectance in
>> >>the visible region (e.g. 545 nm) by using the values of grain size
>> >>previously retrieved. Passive microwave space-borne data at low
>> >> resolution
>> >>will be also eventually used to study the relationships between melting
>> >>onset of snow and soot concentration.
>
>
> Stephen G. Warren
> Department of Atmospheric Sciences     tel 206-543-7230
> University of Washington, Box 351640   fax 206-543-0308
> Seattle  WA  98195  USA                sgw@atmos.washington.edu
> http://www.atmos.washington.edu/warren.html
} % end csznote Warren's concerns

\csznote{ % Talks with Steve Warren and Tom Painter
By summer 2007, beginning of my year 1, Warren will have

1. spectral and concentration measurements from northeast greenland,
   russia, sturm's traverse 

By summer 2008, beginning of my year 2, Warren will have

1. 1st year of air scavenging measurements
2. melt scavenging

Warren already has new data from NPO, Ellesmere, Hudson Bay, Greenland
Summit and the 2000m line.
Collaborating with Sebastian Gerlard from Norway in Svalbard
} % end csznote

\csznote{ % Award notification letter received 20070905
Dear Dr. Zender:

I am happy to inform you that your recent proposal to the Arctic Natural
Sciences Program at NSF has been recommended for funding.
Congratulations on a well-written proposal!

A total of 188 proposals were received for the recent Arctic Systems
Science/Arctic Natural Sciences target date representing approximately
$75 million in requested funding.  These 188 proposals represented 105
different projects.  Additional requests for support of REUs, SGERs, and
for support of proposals submitted to, co-reviewed with, and co-funded
with other programs have also been considered.  Each proposal was
reviewed by experts outside the National Science Foundation and, where
appropriate, by panels.  Approximately $8 million were available to fund
projects submitted to the present competition.  

A variety of factors besides the ratings and, more importantly, content
of reviews of the proposal enter the funding decision: program goals,
the balance of disciplines in the program, logistics capabilities, and
the appropriateness of the work for the Arctic are very prominent ones,
but we must also consider issues of diversity, recruitment of new
scientists, and the broader impacts of awards on society.  Given these
multiple constraints on funding decisions, usually only those proposals
that generate significant enthusiasm amongst the reviewers rise above
the level required for funding.

Please remember that program officers do not make awards.  Only the NSF
Division of Grants and Agreements (DGA) makes awards.  If you have not
yet heard from DGA, you should hear soon, but any expenditures prior to
notification by DGA are made at your own risk.  

The reviews of your proposal and panel review have been released for
your perusal.  I hope that you will read them carefully and take their
suggestions to heart wherever appropriate.  Your proposal was reviewed
by, and is being co-funded by, both the Arctic Natural Sciences program
of the Office of Polar Programs and the Climate Dynamics program of the
Division of Atmospheric Sciences.  The following paragraphs summarize
the Programs' assessment of your proposal.

Intellectual Merit:  The Programs believe that a talented scientist has
proposed a project that is a logical continuation of his prior efforts.
The data sets to be collected during this project will form a
significant community legacy once they are archived.  The anticipated
physics-based modeling of snow-related processes has the potential to
make a significant improvement to future climate models.  The Programs
find merit in many of the constructive criticisms provided by the mail
reviewers.  The PI is urged to consider these carefully and to modify
his approach where this seems appropriate and possible.  Nevertheless,
the Programs concur with the mail reviewer who noted that the project
will make a strong improvement to current understanding if only a
portion of the proposed work is successful.

Broader Impacts:  The Programs believe that the proposed broader impacts
are good.  The PI's institution is a minority-serving institution and he
will use departmental resources to recruit an undergraduate student from
an under-represented minority to work on the project as a year-round
assistant.  The project also will provide support for the training of a
graduate student and a post-doctoral associate.  Finally, the PI will
incorporate results from this project into his lectures for both K-12
teacher education and outreach to informal learning communities.    

After you have digested the content of the reviews and the comments
above, please feel free to contact me, if you have any questions or
concerns.  Again, congratulations on a successful proposal.

Sincerely,
Bill Wiseman
} % end award notification letter

\csznote{ % Reviews of 2006 submission:
Proposal Number: 0714088
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Snow Process Studies and Modeling to Improve Arctic Climate Prediction 
Panel review is contained in above award notification letter

Rating distribution: 
2 Excellent (#s 2, 5), 3 Very Good (#s 1, 3, 7), 2 Good (#s 4, 6)

Review #1
Rating: Very Good

REVIEW:

What is the intellectual merit of the proposed activity?

The proposed work addresses one of the most important science problems
over theArctic; i.e., the impact of aerosols on snow/ice and the
subsequent effect on Arctic climate system. 

The proposer is well qualified for the proposed work, and is well
connected in the broad modeling and data community. For the prior work
supported by a NSF SGER, the progress is impressive. 

The aerosol-snow interaction is a complicated issue. The proposer
intends to use IPY measurements to improve the representation of
snowpack microphysical processes including melt scavenging, hoar
formation, and impurity effects. Then the improved parameterization
will be implemented in climate models to address the aerosol-snow
interaction in the context of Arctic climate system. While no points
in the proposal are necessarily original, integrating the data and
model together still represents a useful and difficult task that is
worth support. 

The real weakness of this proposal is the organization of the proposed
activity. After carefully reading the proposal, it is still unclear
exactly what tasks will be carried out. Section 3 discusses four goals
and associated hypotheses, but it is unclear how each of them will be
addressed by specific tasks. Section 4 (Tasks: Arctic models and
observations) contains nine subsections (or tasks), but it is unclear
what tasks will actually be done by the proposer's team. 

By mixing collaborations with the actual tasks that will be carried
out by the proposer throughout the proposal, and by including too many
materials using the minimum type size, the organization of the
proposed activity is actually weakened. 

The proposer has sufficient access to the necessary resources.

Furthermore, the proposed work is closely related to the IPY
activities, which is a plus. 

Overall, with the proposer's experience and active collaboration with
researcers involved in the Arctic science, some interesting results
are expected. 

Rating for intellectual merit is: Very Good.

What are the broader impacts of the proposed activity?

The proposed project will train one graduate student; the PI will
participate in three programs that provide opportunities to
under-represented minorities; and the PI will participate in K-12
Outreach activities 

The PI is well-connected in the broad data and modeling community. The
proposer will use results from other groups, while results from this
project will be used in some of the major centers/institutions (NCAR,
LANL, GISS). 

Rating for the broad impacts is: Excellent

Summary Statement

The proposer intends to use IPY measurements to improve snow/ice
models used to understand and to predict pan-Arctic climate and
climate change. The proposer is experienced in the proposed research
area and well connected in the community. While it is certain that
some work on data analysis, model revision, and climate modeling
sensitivity will be done, it is unclear exactly what tasks will be
carried out and how these tasks will address each of the four
objectives and associated hypotheses in Section 3. The proposed work
has broad impacts, as indicated by the interest of large number of
collaborators on the proposed work as well as the integration of
research results with educational activities. 

Based on equal weighting of the two criteria, the overall rating is:
Very good/Excellent 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #2
Rating: Excellent

REVIEW:

What is the intellectual merit of the proposed activity?

This is an ambitious proposal well timed with other IPY efforts. The
proposal offers to examine the influence of ice and snow on the albedo
feedback across the Arctic. The work makes use of measurements
gathered for IPY, existing datasets and advanced techniques. The PI is
well prepared to address these issues. The hypotheses and work plan
are well developed. A number of letters of support indicate the
importance of this work. 

What are the broader impacts of the proposed activity?

The work will include one graduate student. The subject matter is of
broad importance to understanding Arctic climate and global climate
change. 


Summary Statement

This project is an ambitious one, well suited to the PI. If only a
portion of the work gets done, the contribution to our current
understanding will be very strong. The broader impacts lie most
heavily on the importance of the subject matter and the likelihood of
the PI to succeed. 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #3
Rating: Very Good

REVIEW:

What is the intellectual merit of the proposed activity?

1) What is the intellectual merit of the proposed activity?
* The scientific and intellectual merit of the proposed work is
  strong. 
* The focus is on an important problem û the ice-albedo feedback in
  arctic regions. Snow impurities may significantly alter snowmelt and
  surface energy fluxes and if trends in energy consumption continue,
  LAC and MD may play an ever-larger role in determining the SSA. 
* Significant progress towards Objectives 1 and 3 are in reach during
  the lifetime of this proposal. Considering the other processes that
  play a role with respect to landscape level fluxes, Objectives 2 and 4
  and more questionable. 

What are the broader impacts of the proposed activity?

2) What are the broader impacts of the proposed activity?
  The broader impact of this work will not be felt in the short-term.
  Until issues as snow heterogeneity have been dealt with û and the
  impact that heterogeneity has on landscape level melt and surface
  water/energy fluxes û this work may not lead to 'better' Arctic GCM
  simulations. However, of those processes that need addressing so that
  better simulations can be achieved - within the next decade û dealing
  with the deposition and impact of snow impurities should be a high
  priority 
 
Summary Statement

Snow Process Studies and Modeling to Improve Arctic Climate Prediction
Zender
Assessment: Very Good

Key words:
Greenhouse gas (GHG) forcing
Light absorbing carbon (LAC)
Mineral dust (MD)

Proposal Summary and Motivation Statements
This project uses IPY measurements to improve cryospheric models used
to understand and to predict pan-Arctic climate and climate change. We
will (1) Use IPY field and lab measurements to improve representation
of snowpack microphysical processes including melt scavenging, hoar
formation, and impurity effects; (2) Implement and/or refine these
processes in Arctic land, atmosphere, and sea-ice components of an
Earth System Model (ESM); (3) Use the ESM to upscale and better
quantify the efficacy of and response to Arctic climate forcing agents
in the 20th and 21st centuries. 

Ice-albedo feedback is arguably the most important positive feedback
in the polar climate system (e.g., Hartmann, 1994; Holland and Bitz,
2003; Qu and Hall, 2006). However, we are unaware of any coupled
global models that account for realistic snow processes, including
aerosol radiative interactions, throughout the surface Arctic 

Net BC [soot] impacts on the Arctic will likely increase through the
21st century. BC emissions from combustion, the primary source of
Arctic BC (Koch and Hansen, 2005) have increased with fuel use over
the past several decades, and are known to within a factor of about
two (Bond et al., 2004). Some scenarios project an increase in
anthropogenic BC emissions of 30-250 in the 21st century (Nakicenovic
et al., 2000). Biomass burning emissions may increase due changes in
fire regime though this is highly uncertain (Thonicke et al., 2005;
van der Werf et al., 2006). Present day dust emissions and deposition
are known to no better than about a factor of four globally (Zender et
al., 2004). Whether there is currently a trend in global mineral dust
emissions is not knownùincreasing (from anthropogenic activities) and
decreasing (due to CO2 fertilization of vegetation) trends are both
plausible (Mahowald and Luo, 2003; Tegen et al., 2004). 

Strengths:
The proposed work identifies an important problem; that snow
impurities, especially light absorbing carbon (LAC) and mineral dust
(MD), can have a large impact on snow surface aging (SSA) - and that
this impact has not been explored in any detail. Most snow models used
in GCMs employ relatively simple parameterizations to capture snow
surface aging, and the associated changes in the surface albedo. The
most common parameterization is based on Army Corps of Engineering
data taken a half century ago, where the snow surface albedo
exponentially declines from ~.85 to ~0.5 after a number of days
without snow freshening. The albedo is reset to 0.85 after a new snow
event. This new work proposes to employ more physically robust
algorithms to account for the surface albedo changes due to the
effects of LAC and MD. The researches have the expertise to follow
through on most of the objectives and present a logical progression of
research: from incorporating SINCAR with the CSM, to using in-situ
measurements, to incorporating remote sensing (MODIS). 

Weakness:
There is no specific scientific weakness. However, the notion that
this will significantly improve arctic simulations in the near term is
debatable: 1) Contrary to the notion presented here, multi-layer
models have been developed and are currently in use in GCMs û many owe
much of their physics to SNOTHERM. They allow thermal profiles to
develop, which in turn, impact internal thermal properties,
etc. Offline testing has shown these models can reproduce the thermal
profile within the snow, the insulation provided by the snow (by
monitoring of ground temperatures), and can achieve the correct
seasonal timing of snow melt. When coupled to GCMs, these models have
also been able to reproduce simulate the aerial extent of seasonal
snowcover. 2) Snow heterogeneity in the arctic is significant, and in
some regions, show strong year-to-year variability. More to the point,
this heterogeneity is below the MODIS length scale. Until this is
resolved, it is questionable whether, inclusion of dirty snow will
improve simulations significantly. 3) A still unresolved issue is that
of the snow surface sublimation-condensation and the impact this has
on the snow surface albedo and surface energy exchange. Will
incorporating for the effects of LAC and MD significantly improve the
surface and internal snow processes above and beyond what has
currently been achieved? My own view is that until the heterogenity
issue is properly dealt with, there will not be significant progress
in representing landscape level surface water and energy fluxes at
high latitude systems. 

Assessment:
The two Merit Review Criteria used are:
1) What is the intellectual merit of the proposed activity?
* The scientific and intellectual merit of the proposed work is
  strong. 
* The focus is on an important problem û the ice-albedo feedback in
  arctic regions. Snow impurities may significantly alter snowmelt and
  surface energy fluxes and if trends in energy consumption continue,
  LAC and MD may play an ever-larger role in determining the SSA.

* Significant progress towards Objectives 1 and 3 are in reach during
  the lifetime of this proposal. Considering the other processes that
  play a role with respect to landscape level fluxes, Objectives 2 and 4
  and more questionable.

2) What are the broader impacts of the proposed activity?
* The broader impact of this work will not be felt in the
  short-term. Until issues as snow heterogeneity have been dealt with û
  and the impact that heterogeneity has on landscape level melt and
  surface water/energy fluxes û this work may not lead to 'better'
  Arctic GCM simulations. However, of those processes that need
  addressing so that better simulations can be achieved - within the
  next decade û dealing with the deposition and impact of snow
  impurities should be a high priority 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #4
Rating: Good

REVIEW:

What is the intellectual merit of the proposed activity?

The proposer has excellent expertise in aerosol modeling, black carbon
cloud physics, and radiative transfer modeling. There appear to be
some knowledge gaps in the proposal regarding arctic snow, sea ice,
and albedo. There is prior work on snow stratigraphy and snow albedo
evolution that is relevant to the author's approach concerning the
importance of metamorphism on large-scale albedo. 

Several excellent partnership are proposed (Domine, LANL, CCSM) that
should be quite productive. Other partnerships beyond the laboratory
and modeling communities might be useful. 

The proposal focuses on the impact of black carbon and of snow
metamorphism on the albedo of polar snow. The case for the black
carbon studies is strong. A little bit of black carbon goes a long way
in reducing snow albedo. This could have significant impact on
large-scale polar snow albedo, particularly in the Arctic with
abundant northern hemisphere BC sources. 

The motivation for the metamorphism studies is less evident. A highly
detailed approach to modeling temperature gradient metamorphism,
surface hoar formation, and diurnal cycling and the consequence
changes in the specific surface area of the snow is proposed. However,
the impact of wind blown snow on snow microstructure is not
considered. The proposal does a good job of identifying the large
temperature gradients present in polar snowpacks and considering snow
metamorphism. But what about the impact of wind and blowing snow on
snow structure? This is a major factor in the small scale structure of
polar snowpacks. More discussion of the observed properties of polar
snowpacks would be helpful. Is extensive TG metamorphism evident? What
do the observations of snowpack stratigraphy show? 

A few minor comments:
1. More explanation of "efficacy" would be helpful. In particular the
  idea of per unit forcing: how is a unit of CO2 compared to a unit of
  BC. What are the units used for comparison?
2. Extend the spectral measurements beyond 1310 all the way to 2500
  nm. Good instruments are available over this spectral range.
3. Many other explanations, besides black carbon, have been given for
  the polar asymmetry in sea ice change.
4. A sentence describing Painter's method for quickly determining SSA
  would be useful. 
5. Additional information on the optical measurements made in
  conjunction with the SSA observations would be useful. Spectral
  reflectance measurements are mentioned, but at what angle and
  instrument field of view? Will a suite of reflectances at different
  zenith and azimuth angles be measured? How about transmission
  measurements? 

What are the broader impacts of the proposed activity?

The scientific broader impacts are very clearly defined. SNICAR model
seems to be a powerful tool and a vital part of this proposal. There
is excellent integration of models on different scales from SNICAR to
CICE to CCSM. Outreach activities include a graduate student and a
post-doc. Other broader impacts are limited. 

Summary Statement

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #5
Rating: Excellent

REVIEW:

What is the intellectual merit of the proposed activity?

Snow cover strongly interacts with Arctic climate through snow-albedo
feedback. Snow aging due to deposition of dust and black carbon (soot)
may strengthen the feedback. The proposed work addresses very
important questions with regard to the impacts of various aerosols on
snow surface albedo, Arctic sea ice ablation, and Arctic warming. The
proposed activities will certainly advance our understandings of the
relative contributions of snow-albedo feedback and aerosols in snow to
Artic warming, compared to the contributions of GHG forcings. The PI
of the proposal is well qualified for leading the project as reflected
from his extensive experience in global aerosol modeling, ice cloud
physics, and aerosol optics as well as his previous NSF SGER projects,
which developed the SNICAR. The proposed activities include lab
experiments, field experiments, model simulations, and extensive uses
of satellite data through collaborations with national and
international scientists. The activities are well conceived and
organized as evidenced from letters of his collaborators. 

However, I would like to suggest the proposer acknowledge the efforts
in snow model developments during the past decade and developments in
representing other important snow cover processes, such as, subgrid
distributions of snow cover, vegetation sheltering effects on snow
cover, blowing snow, etc.. The snow model in CLM is a multi-layer and
physically-based model and represents one of the best snow models in
current GCMs. 

What are the broader impacts of the proposed activity?

The proposed studies will have broader impacts on researches including
Arctic climate, terrestrial hydrology, wetland and CH4 emissions, and
biology. It may contribute to IPCC assessments of various
anthropogenic forcings. I am certain that the advanced SNICAR will be
incorporated into the NCAR community atmosphere and land models and
also be released to broader users. Additionally, the project will
provide trainings to a undergraduate student from underrepresented
minorities, post-doc, and K-12 teachers. 

Summary Statement

The proposed work addresses very important questions with regard to
the impacts of various aerosols on snow surface albedo, Arctic sea ice
ablation, and Arctic warming. Overall, the proposal is very well
written and the proposed research activities are well organized. The
PI has actively interacted with various scientific communities and is
well qualified for leading the proposed activities. I suggest the PI
be aware of activities in snow modeling communities during the
proposed period if it is funded. 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #6
Rating: Good

REVIEW:

The proposal is not written in accord with NSF guidelines. The PI
missed to include full citations of publications and presentations
resulting from awarded or funded NSF project. 

The proposal makes the impression being written with a hot
pen. Abbreviations are used before being explained some paragraphs
later; the formatting is very messy and the small hard to
read. Furthermore, asking for an unfunded wrap-up to begin with means
that the work cannot be done in the time funding is asked for. Where
does the funding for the unfunded wrap-up come from? Is here already
the supplemental proposal thought off and planned for because the call
does not permit him to ask for 4 years or the cost becomes too high
that he thinks it would reduce the chances for getting funded at all
if funds are asked for 4 years? Over wide ranges of the proposal it
remains unclear whether the main purpose is to further develop SNICAR
or develop a better snow module for CCSM. 

According to the proposal title the PI obviously is not a climate
modeler also he claims so. In climate modeling, one talks about
climate projections or scenarios, but not climate prediction. The
research on the scientific background is well done with respect to
snow physics models, but not with respect to CCSM. To my best
knowledge CCSM uses CSIM as sea-ice model, not CICE. CCSM has no
glacier model component. It treats glaciers as one of four land-cover
types within the framework of the Common Land Model. Despite reading
the proposal several times it remains foggy whether the intent is to
develop an improved snow module for CCSM or implementing SNICAR with
CICE. 

Despite these technical writing aspects are not NSF criteria, I think
that they are worth mentioning. My following evaluation bases on NSF
criteria only. However, I may have missed some important
points/aspects due to the way the proposal is written. 

Scientific merit:

The proposed work will integrate observational studies, high
resolution snow pack modeling and climate modeling to improve snow
process modeling in Arctic climate predictions and to investigate the
snow-aerosol feedback. 

Including temperature gradient driven snow metamorphism in CCSM is of
high scientific merit because the current snow physics are very
simple. It will provide a more realistic description of snow processes
in Polar Regions. The PI intends to identify the contributions of
aerosols and greenhouse gases as Arctic forcing agents and to identify
their impact on snow-pack life cycle. Doing so is of high merit for
any snow physics models. 

The proposed work would provide the first dataset that holds
simultaneous SSA and reflectance measurements. Such a dataset may be
of importance for better understanding snow processes and development
of new parameterizations. 

The methods suggested remain very foggy to unclear with respect to how
the different scales are to be bridged and how the different data
sources and models are to be linked. Furthermore, there are several
unaddressed issues. Most snow packs in the Arctic do not experience
melt/freeze cycles before spring. May be it is just misunderstandably
written, but except for high elevation, snow on the Arctic sea-ice and
Greenland there is no snow in the Arctic that can be affected by
particles from boreal forest biomass burning that occurs in summer
only. Other shortcomings are that no sea-ice retreat effects and
interaction with soot will be considered because the PI intends to use
sea-ice from data. This means that in simulations without soot effect
the soot is indirectly included in the forcing data for the lower
boundary condition. The observed sea-ice distribution as is/was
evolved with the soot. Moreover, recent studies showed that the
sea-ice retreat is dynamically driven. 

The model physics of CLM and SNICR differ. I am worried about
inconsistencies in the radiative transfer as treated in the two models
and their impacts on the results. I am well familiar with Domine s
data, they are excellent and well documented. They are suitable for
snow physics models, but I strongly believe that they are unsuitable
for the purpose of the proposed study. A snow physics model is too
complex to be run in CCSM with today s computational resources. 

In summary, the idea is good, but not achievable in the anticipated
timeframe with the group size in mind. It is high risk because the PI
depends on so many other people to get funding to provide elements he
needs to do the proposed work. I highly recommend cleaning the
proposal up, adding more human power and resubmitting a revised
proposal as a collaborative proposal. I would rate the proposal good
if all the others were funded, undoable if not. 

Rating: average

Broader impact:

Broader impacts come more like an after thought than being a real part
of the proposal. Having a graduate student and a undergraduate student
will mean great broad impact on the society. He is also involved in
school curricula. Improving the education at the high school level is
an urgent need for staying competitive internationally. Thus, his work
has a broad impact along this line. 

Rating: good

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #7
Rating: Very Good

REVIEW:

What is the intellectual merit of the proposed activity?

I believe this proposed work would represent a significant
contribution in advancing our knowledge regarding light absorbing
carbon, dust, etc. in snow-covered regions. Indeed, these processes
are currently not being considered in general circulation models
(GCMs), which represents a significant shortcoming as these are
crucial processes. In fact, most crucial high-latitude processes are
not currently considered in GCMs, therefore any activity to improve
these shortcomings is highly commendable. The proposer and his
collaborators are certainly highly qualified to conduct this work, as
it represents their primary specialty. This is reflected in both their
previous work, as well as their overall 'reputation.' This represents
the 'strengths' of the proposal. 

In terms of potential weaknesses, it seems some of the observational
data that will be used to improve modeling capabilities will be based
on laboratory experiments (section 4.2)? While this is certainly
useful, I would prefer to see more emphasis placed on actual real
world observations. This is a minor weakness, since obviously it is
not feasible or even possible to come by actual observations for many
of the parameters to be evaluated, and the proposers will use actual
in situ observations as well, as outlined in sections 4.3-4.8. 

Lastly, a concern I have with the proposal is that there is no
statement regrading the proposer's data management/archiving plans (I
thought this is now required by NSF?). Hopefully any/all data sets and
data products to come out of this investigation would be properly
archived at a place like the National Snow and Ice Data Center, and
therefore freely available to the scientific community? 

What are the broader impacts of the proposed activity?

The broader impacts of this proposed project are also highly
commendable. Not only does much of the proposal utilize work done by a
student (SNICAR), but an additional student as well as a postdoc will
be trained as a result of this work. The PI trains K-12 teachers in
Earth Sciences, and including the type of science that is considered
in this proposal would certainly contribute greatly to the training of
teachers and hence K-12 students. As also stated in the proposal,
UC-Irvine is known for its minority participation and involvement. In
addition to these obvious educational impacts of the work, as stated
above in the intellectual merit section, this work has the potential
to significantly improve modeling capabilities, and hence our
abilities to predict future high-latitude changes. I believe this
proposal to have excellent broader impacts. 

Summary Statement

In determining my overall evaluation of this proposal, I placed ~2/3
emphasis on the intellectual merit, and ~1/3 on the broader
impacts. Overall, I find this proposal to be very good given the
potential impact it may have on improving modeling
capabilities. Furthermore, this proposal ranks very highly in terms of
its broader impacts. I believe this proposed work should be supported
if at all possible. 
} % end csznote

\csznote{ % Reviews of 2005 submission:
Proposal Number: 0612954
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks 

Rating distribution: 
3 Excellent (#s 1, 2, 5), 1 Very Good (#s 3), 1 Good (#s 4)
(Review #3 was most informative, not counted due to conflict of interest)

Panel Summary #1

The overall objective of this proposal is to estimate the influence of
absorbing aerosol (biomass burning, soot, and dust) deposition to
Arctic snow and sea ice on Arctic climate. The proposal seeks to use a
GCM coupled snow model (SNICAR) developed by the PI that will estimate
the deposition and transformation of absorbing aerosols to snow. As
pointed out by the PI, snow chemical/physical dynamical properties are
extremely important and the model does take these processes into
consideration. Although a weakness is that there are probably many
parameterizations that need to be validated (i.e. the link between
snow chemistry and grain growth). The proposal will also bring
satellite retrieval of grain size and absorbing aerosol into play, and
will couple with other IPY proposals (Very Good). 

The panel had a chance to review the proposal and the mail reviews. 
The mail reviews were largely positive (3 Excellent, 1 Good) which
cites the potentially significant impact of this work on climate
feedbacks related to black carbon. This also brings a new researcher 
into the study of arctic research and modeling. The Good review cites
the limitations of obtaining the sensitivity of albedo from satellite
data based on a small change in snow from black carbon. However, the
panel sees this as an improved step to attempt to validate this BC
effect over what previous GCMs have modeled in overly simple
methods. The proposed PI has a good record of making connections and
tools for the GCM community that will help in the integration of this
physics into GCMs.

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #1
Rating: Excellent

REVIEW:

What is the intellectual merit of the proposed activity?

Will clarify a role of black carbon on the Arctic snow and ice and on
the Greenland ice sheet. 

What are the broader impacts of the proposed activity?

Improved understanding of the role of black carbon on climate. This is
essential to understand many questions connected to Arctic climate;
for example why is the melt area of Greenland ice sheet increasing? 

Summary Statement

Very well written proposal that will impact our knowledge concerning
Arctic climate. PI is well qualified to accomplish proposed research. 
The results will be important for future AOGCM modeling.

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #2
Proposal Number: 0612954
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks 
Rating: Excellent

REVIEW:

What is the intellectual merit of the proposed activity?

1.) Intellectual Merit: This proposal addresses an important element
of Arctic System energy exchange, the effect of soot and dust on the
albedo of snow and ice. It is a model improvement proposal (i.e.,
there is no field work) and the outcome is a diagnostic or process
model (SNICAR) that will inform (but not be directly incorporated
into) large climate system models. That is probably a good thing as
the topic is complex and the larger models are not yet ready to for
the level of sophistication that the investigators should be able to
achieve in their work (and which is needed to understand the effect of
the soot and dust). One of the strengths of the proposed work is that
the investigators have been working on the topic of soot, dust, and
snow for some time. They have produced a solid string of papers on the
topic, are well connected to other modeling efforts, and have
developed a structure through which they can disseminate their
findings. In short, the proposed work is likely to be effective in
producing results on a topic of importance. It should be funded. 

What are the broader impacts of the proposed activity?

2.) Broader Impact: There is some evidence to suggest that fires and
dust storms could have as great, or a greater impact, on the arctic
climate than greenhouse gases. Given the intense national and
international efforts to identify and quantify the impact of
greenhouse gases on climate, it is equally important to investigate
these other sources of climate forcing. It is also important that we
understand how these forcings work: the devil may be in the
details. The investigators have a reasonable chance of producing an
advance in this area by focusing on the topic, producing a stand-alone
model, and incorporating the results into the larger model CCSM. 

Summary Statement

3.) Recommendation: Excellent proposal. Fund it.

But here are some suggestions the investigators should consider:
a. Snow grain size and soot: What is the evidence that soot or dust
change the process and growth rate of equilibrium snow grains? My
sense is that this is a first order thermal process driven by spring
weather with percolation of melt water far more important than
microscopic amounts of soot. By all means, the investigators should
look at whether the soot produces enough radiation heating to
materially affect the grain size, but I doubt it. They should keep in
mind that on the sea ice and on the tundra, the melt comes on so fast,
there isn't that much time for minor differences in albedo to have
much of an impact. 
b. Mixed Pixels: How do the investigators plan to deal with this
issue? We know that for sea ice the distribution of melt ponds and
open water has a profound impact of the 'scene albedo'. Similarly, for
tundra and taiga, bare patches and exposed vegetation lowers the scene
albedo more than soot or dust. Only in Greenland is the mixed pixel
problem less important. The proposal has a major focus on Greenland,
but the investigators should not neglect the rest of the Arctic
terrestrial and marine area. 
c. Where is the soot and when? The snow aging section of the proposal
seems overly simplistic to me (and I have watched a lot of arctic snow
melt, on land, on sea ice, and on glaciers). My suggestion is to go at
this complex set of events using time as a weighting factor. O.K.,
each melt season is different, but broad generalizations can be
made. How much time does the snow spend in the pre-melt period? How
much solar energy is available during that phase? Does downward
percolation remove (or concentrate) the soot quickly? Once scrubbed of
soot, how long is the surface snow clearer and therefore higher in
albedo? I urge the investigators to confirm with experts on the melt
and keep an open mind as to what is and isn't important. For example,
why is sintering important with respect to soot/dust and albedo? Seems
like a less important process than many others. There are also scaling
issues inherent in this issue. The processes take place locally, at
scales that are order meters. The modeling seems to be at scales that
examine tens of kilometers. How to ensure that the latter aggregate
linearly at the latter scales? The collaboration with the
Warren-Grenfell group is a step in the right direction, but even a
closer connection with snow process researchers would help guide the
proposed research better. 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #3
Proposal Number: 0612954
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks 
Rating: Not Available

This review was determined to represent a Conflict of Interest and was
NOT used in the decision-making process. 

REVIEW:

What is the intellectual merit of the proposed activity?

The goal of this project is "to use a theoretical radiative model for
snow, ice, and aerosols to assess absorbing aerosol interactions in
the coupled Arctic climate system using models which represent the
complex surface lifecycles of Arctic snow, black carbon, and dust." 

Intellectual merits of the proposed activity are listed as follows:
a) Potential for Arctic BC to disrupt summertime sea-ice formation.
b) Role of boreal fire variability in Arctic reflectance, particularly Greenland
c) Relative roles of Arctic soot and dust in inducing surface melt,
heating and darkening. 
d) BC content is to be addressed in the context of preindustrial,
present day, and next century time scales. 

Strengths û This study would contribute to the development of a
significant model for understanding small scale snowpack metamorphism
processes affecting grain growth, their interaction with BC deposited
in the snow, and the implications for snowpack albedo. Zender and
colleagues have already done a significant amount of development on
the basic snow model. While there are still significant issues to
check with respect to equi-temperature and temperature-gradient
metamorphism, I feel that this model is coming along nicely and would
be quite useful for (i) interpreting surface-based and satellite
observations of BC-laden snow and (ii) coupling the evolution of
snowpack properties driven by radiative and for convective forcing
with wavelength integrated and spectral albedo. Including better
physics into GCM models is critical if we expect them to actually work
well one day. 

Weaknesses û I found the proposal somewhat diffuse and lacking in
clarity in a number of places. Based on my field and theoretical
experiences, I feel that there are also a number of misconceptions
about the physics of sea ice and its snow cover that will need to be
addressed. These are not critical for the work done to date on the
model, but they will need to be handled properly. My concerns are
covered in more detail in the summary statement. The proposer should
know about two existing surface based observational data sets of BC in
the Arctic snow pack which indicate that the BC levels in the Arctic
are very likely lower now than in the early 1980's. The statement that
the BC levels in the snow are increasing steadily thus needs to be
clarified. I don't see any mention of the SNOWTHERM model, which I
suspect has large areas of overlap with SNTHERM could be made to host SNICAR.
the proposed UCI model. 

Specific comments:
Summary and in the Project Description: "to disrupt summertime sea-ice
formation û I'm wondering what the deal is here. Summertime in the
Arctic Basin is broadly defined as the season when the sea ice is
melting, and it's well documented that melting is by far the dominant
mode during June, July, and the first half of August. The potential
for BC would be to extend the length of the melt season rather than
inhibit ice formation during that time. 

'BC is slowly increasing in the Arctic'. The author appears to be
unaware of two surface-based studies of BC (Grenfell, Light, & Sturm,
JGR, 2002; Grenfell & Perovich, JGR, 109, 2004) showing that present
BC levels on certain areas of Arctic sea ice are significantly lower
than in the early 1980s. 

Lowering the albedo of the ice grains themselves û unclear. Ambiguous
use of albedo? Single scattering albedo is not the same as surface
albedo. 

Figure 1 is obscure and confusing. You should at least explain the
symbols and expand the description in the caption. What does it mean
to "mediate" a feedback. Does this mean 'cause' or 'suppress'? 

Figure 2 û In JJA there isn't much snow on the Arctic sea ice. In
addition to the fact that the snow cover melted away in early to mid
June (this was well documented during the SHEBA experiment in 1998),
there were large areas of open water at the margins of the basin
during most of the JJA period in both 1997 and 1998 where the model
shows large BC forcing. I could see large forcing from forest fires in
say AMJ, but after that, in the open water, the albedo is already
0.067 or so, all due to surface reflectance. So adding soot, even in
rather large quantities, should make very little difference. If the
model simply assumed the presence of snow and calculated forcing on
that basis, the numbers aren't particularly meaningful. The plots in
figure 2 thus needs explanation. 

Internal snowpack melt. Brandt and Warren studied this in detail, JGR,
39, 1993, and concluded that the solid state greenhouse effect in snow
is very small at best. They showed that a detailed spectral radiative
transfer model must be used in an analysis of this effect. Personally,
I have never observed significant internal snowpack melt that wasn't
accompanied by surface melting. Although one can no doubt construct
plausible scenarios, I don't think it is an important medium to
large-scale effect 

'Previous effortsà disallow some important feedbacks that occur in
Nature (sic)' û What do you have in mind here? 
'will result in a more complex and interactive Arctic system whereà' û
it's not the system but the model that will be more complex. 

By 'boreal soot' I assume you mean soot from boreal fires. Boreal
simply means "northern", of course, which could be the meaning here,
but it would be redundant since your focus is limited to boreal
areas. It would be good to be a bit more precise about what would
actually be studied. 

Figure 4 û what's all the nomenclature at the top of the right-hand
panel. "due to 1998" û what is it about the year 1998 that affected
r(eff)? 

Atmospheric BC cools the surface by backscatteringà - I think
backscattering from soot is negligible compared with the cloud
droplets that are quite ubiquitous in the Arctic summer
atmosphere. I'm sure any cooling of the surface is virtually all due
to absorption. Artic haze looks dark. 

Thinnest ice category is the most susceptible.. û the thinnest ice has
very little snow on it as a rule. 

Significant changes appear as cross hatched regions in Figures 4 and 5
û Be careful here. It is improper statistical technique to say that
part of a distribution is significant in the context of analyzing the
whole data set, i.e. that there are certain areas in a pattern with
"significant variations" relative to other areas. The statistical test
tells you whether you can believe your hypothesis for the entire
distribution, not just for a part of it. In a noisy comparison, one
can almost always find a big variation that are apparent, but its
significance isn't a local matter. The analog in one dimension is does
a linear regression match the data to say the 95\% confidence level,
for example. In that context you can't say anything meaningful about a
subset of the regression that matches particularly well (or poorly). 

Pg 12 û Since soot concentrations rarely exceed 5 micrograms/kg in
Greenland û this is probably true, but how do you know what the value
is? This is pretty close to the background value for the snow on sea
ice in the central Beaufort Sea. Are these relatively low values
rarely exceeding 5 consistent with a steady increase with time? 

What are the broader impacts of the proposed activity?

Broader impacts of the proposed activity. Listed are:
a) Understanding of Arctic hydrology
b) SNICAR model would be made widely available to the scientific
community û in the CCSM and in independent form for process study
applications. 
c) Contributions to glacier mass balance, basin and catchment
hydrology, sea-ice lifecycle, paleoclimate sensitivity, and snow
chemistry. 
d) K-12 teacher training program and presentations for lifelong
learning students. 
These are all valid broader impacts, and I think the proposer would
make a serious effort on the outreach component of the
project. However, I think that more important than any of these are
the implications of BC for large scale radiative forcing of the arctic
atmosphere and the surface snow cover. I note that a BC content of 5
micrograms/kg is not enough to lower the snow albedo by 0.01, a level
that is comparable to the observational uncertainties of the albedo of
snow-covered surfaces. 

Summary Statement

I rate this proposal as VG minus. I think it would be very valuable to
have a working model of this sort available to the geophysical
community at large, and I believe this snow model makes a serious
effort to include the physics of snow metamorphism correctly. I have
some reservations related to the comments I provided in the
intellectual merit section that need to be addressed. 

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #4
Proposal Number: 0612954
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks 
Rating: Good
REVIEW:

What is the intellectual merit of the proposed activity?

This proposal focuses on absorbing aerosol interactions in the Arctic
climate system using the SNICAR model for the complex surface
lifecycle of Arctic snow, black carbon, and dust. The study field is
limited within Greenland, which is not representative of the
pan-Arctic. 

The PI addresses the effect of dirty snow on land, glaciers and
sea-ice and the role of the Arctic BC; however, the proposal is
insufficient in its the presentation on land and glaciers. For
example, the snow density, snowpack temperature and snow water
equivalent (SWE) along the tundra and boreal forest of Alaska during
the winter change remarkably with time, and AMSR-E retrieval is quite
different from in-situ data for the representation of SWE, which is
due to thicker wind clusters (> 10 cm) and well-developed depth hoar
at bottom snowpack despite less than 40 cm snow depth in the tundra of
Alaska. For these reasons, I questioned the SNICAR is questioned model
can reproduce the Arctic climate system sufficiently. 

What are the broader impacts of the proposed activity?

Because this proposal includes unpublished citations, such as AGU
abstracts and submitted manuscripts that may play significant roles in
assessing the Arctic climate system, it was difficult to review. 

The objectives and hypotheses in the proposal regard the fate of
Arctic BC related to boreal fires. In fact, many scientists have
described and demonstrated the importance of anthropogenic BC rather
than wildfire BC, which makes up a much smaller fraction than the
fossil fuel and biofuel BC in Asia. According to Koch and Hansen
(2004), the BC deposition in Greenland is dry, not wet scavenging as
the PI described. The SNICAR model that merged sea-ice and ice-sheet
models is in the PI's responsibility, not graduate students'. 

Lacking are any innovative programs with broader impacts that involve
recruiting minority students or related activities. 

Summary Statement

Overall, I found the goal to be admirable, but the project to be unfundable.

%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%%

Review #5
Proposal Number: 0612954
Performing Organization: U of Cal Irvine
NSF Program: Arctic Natural Sciences
Principal Investigator: Zender, Charles S
Proposal Title: Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks 
Rating: Excellent
REVIEW:

What is the intellectual merit of the proposed activity?

The proposal addresses determination of the spectral snow albedo
dependence on snow physical parameters such as snow age, depth,
density, temperature, temperature gradients, grain size, and more
importantly, absorbing (soot) inclusions. Since the interaction of the
different physical parameters is decidedly non-linear, a comprehensive
radiative transfer model (that also can model the atmospheric spectral
dependence) is required to properly analyze the interactions. The
modeling of snow over sea ice will also be addressed in the proposed
research. 

What are the broader impacts of the proposed activity?

Accurate simulation of snow albedo over different surface types is
important for accurate climate change modeling, especially in the
polar regions where the local surface heating and cooling rates have a
strong influence on snow-ice feedback effects. A good benchmark model
is needed before effective parameterizations for snow albedo
dependence on snow physical properties and soot inclusions can be
accurately included in GCM simulations. A good snow albedo model is
also needed to effectively interpret satellite (MODIS, MISR)
retrievals of snow covered areas. 

Summary Statement

The investigator has previously demonstrated expertise in modeling and
interpreting spectral measurements of snow albedo, as well as
expertise in radiative transfer modeling of aerosol and cloud effects
on the downwelling radiation field. A quantitative determination of
soot inclusions on snow albedo is important for improved climate
change modeling in the polar regions. There is adequate post-doc and
graduate student participation in the proposed research project. The
proposed research tasks are well defined. I therefore recommend that
the proposal be funded. 

} % end csznote

\csznote{
# Dozier's pubs
http://www.snow.ucsb.edu/REASoN-Publications.htm

# Email distribution list
Siri Jodha Singh Khalsa <sjsk@nsidc.org>,
Tom Painter <tpainter@nsidc.org>,
Jim Randerson <jranders@uci.edu>,
Mark Flanner <mflanner@uci.edu>,
Jorge Talamantes <jtalamantes@csub.edu>,
Charlie Zender <zender@uci.edu>

% Letter sent to Bill Lipscomb 20051215:
Dear Bill,

Thanks for discussing collaborations on the phone yesterday.
As I said, I am following up with a one page summary of our proposed
NSF project, and some sample text should you choose to endorse our
collaboration more formally with NSF. Please feel free to
ruthlessly alter/edit! The below text is meant to save you time, not
to constrain you or to obligate you to do work you're not already
interested in. If you choose to write such a letter, it would be
most helpful if you could e-mail me a PDF on your letterhead by
Wednesday morning 12/21, although a simple e-mail will suffice if you
are too busy for the deluxe PDF option.

Thanks!
Charlie

"Dear Charlie,

As one of the principle developers of the Los Alamos sea-ice model
(CICE), a primary component of the
National Center for Atmospheric Research (NCAR)
Community Climate System Model (CCSM),
I have a great interest in understanding and correctly representing
the coupled cryosphere in Earth System Models.
Your proposed NSF project "Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks" would
continue to advance the state-of-the-art in snowpack radiative
transfer which provides an important upper boundary condition in the cryosphere.
We are happy to collaborate with you and Mark Flanner in two related
areas during the NSF project.

First, we are implementing a multi-layer snow thermodynamic model to
improve the current single layer snow model in CICE.
We will provide source code access and advice on technical details
so that your project can merge SNICAR physics for snowpack aging and
radiative processes into CICE.
Second, we are developing an interactive ice sheet component, based
on GLIMMER, for the CCSM.
We envisage using the a form of the Community Land Model (CLM) and its
snow model with SNICAR as the upper boundary condition.
The integrated treatment of clean and dirty snow in the cryosphere
which will result from our complementary efforts will provide a
state-of-the-art toolkit with which to study the scientific questions
posed in your proposal."

% Letter sent to Steve Warren 20051215:
Dear Steve,

As I said, I am following up with some sample text should you choose
to endorse our collaboration more formally with NSF. Please feel free
to ruthlessly alter/edit! The below text is meant to save you time,
not to constrain you or to obligate you to do work you're not already
interested in. If you choose to write such a letter, it would be
most helpful if you could e-mail me a PDF on your letterhead by
Wednesday morning 12/21, although a simple e-mail will suffice if you
are too busy for the deluxe PDF option.

P.S. As I think you already know, SNICAR uses optical properties based
on your and Grenfell's work on the surface-area-to-volume Mie
approximation. Thanks again for developing this useful approximation!

Charlie

"Dear Charlie,

As you know I have a great interest in understanding snow, ice, and
Arctic aerosol properties and I approach these topics from a
combination of laboratory and in situ measurements combined with
radiative transfer modeling.
Your proposed NSF project "Dirty Snow on Land, Glaciers, and Sea-Ice:
Understanding Arctic Absorbing Aerosol Forcing and Feedbacks" would
continue to advance the state-of-the-art in snowpack radiative
transfer which provides an important upper boundary condition in the
cryosphere. Moreover, your coupled snowpack aging and radiation model,
SNICAR, is a very suitable tool for hind-casting the snowpack BC
concentrations in Greenland which our group continues to measure.

Our newly proposed NSF project "title goes here" will fund us to
measure BC from snow samples collected at all Koni Steffen's AWS
sites, which will provide good coverage of the Greenland ice sheet. 
We will be pleased to provide your project with these measurements and
to collaborate on their interpretation.
The synergy between our measurements and your modeling project
to understand and represent Arctic snow-ice-aerosol feedbacks is
exciting."

% Letter sent to Phil Rasch 20051215:
Hi Phil,

We are writing an NSF Arctic proposal called "Dirty Snow on Land,
Glaciers, and Sea-Ice: Understanding Arctic Absorbing Aerosol Forcing
and Feedbacks". The proposal would fund a grad student, and a one year
postdoc which Mark Flanner can use as bridge funding. The goal is
to continue studying dirty snow, both BC and dust, and to move to
the next level of feedbacks by really including sea-ice and glacier
effects. We think we have land pretty well covered, and will work
with Bill Lipscomb (and probably Bruce Briegleb, although I'm a bit
unsure where that stands) on the sea-ice and glacier coupling to
SNICAR.  

Mark is beginning to write a boreal soot manuscript on which you will
be offered co-authorship. Not making you an official co-author on the
study Mark presented at AGU was an oversight! Although we fixed it in
the title slide your name was not in the program. Apologies.

Back to the present. This proposal is due Thursday 12/22 (I got an
extension to improve the collaboratory aspects of the proposal).
This proposal will rely heavily on continued use of your BC aerosol
model in CAM. I am verifying that we can rely on you for this,
and that I can mention this in the proposal's collaborative portion.
Is there anything I should know or that you'd like to add?
Attached is the current one-page summary FYI.

Thanks,
Charlie

% Letter sent to Natalie Mahowald 20051215:
Hi Natalie,

We are writing an NSF Arctic proposal called "Dirty Snow on Land,
Glaciers, and Sea-Ice: Understanding Arctic Absorbing Aerosol Forcing
and Feedbacks". The proposal would fund a grad student, and a one year
postdoc which Mark Flanner can use as bridge funding. The goal is
to continue studying dirty snow, both BC and dust, and to move to
the next level of feedbacks by really including sea-ice and glacier
effects. We think we have dirty land-snow pretty well covered, and
will work with Bill Lipscomb (and probably Bruce Briegleb, although
I'm a bit unsure where that stands) on the sea-ice and glacier
coupling to SNICAR.  

This proposal is due Thursday 12/22 (I got an extension to improve the
collaborative aspects of the proposal). 
This proposal will rely heavily on continued use of Phil's BC aerosol 
model in CAM and on your dust code, if you agree. 
May we rely on you for code access and advice as has been our habit?
It would be especially cool to include your glaciogenic dust sources
(pun intended). Of course, we'll offer you co-authorship on any of the
dust-related results. 
If you agree, may I mention this in the proposal's collaborative portion?
Is there anything I should know or that you'd like to add?
Attached is the current one-page summary FYI.

Thanks,
Charlie
} % end csznote

\csznote{ % Proposal preparation: 
/bin/cp ${DATA}/ps/bio_nsf.pdf ${DATA}/prp/prp_ans/prp_ans_cv_zender.pdf

# Summary + Project Description + References
pdftk A=${DATA}/ps/prp_ans.pdf cat A4-33 output ${DATA}/prp/prp_ans/prp_ans.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A22 output ${DATA}/prp/prp_ans/prp_ans_scd.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A4 output ${DATA}/prp/prp_ans/prp_ans_smr.pdf
# Collaborator tasks
pdftk A=${DATA}/ps/prp_ans.pdf cat A14 output ${DATA}/prp/prp_ans/prp_ans_tsk_domine.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A17 output ${DATA}/prp/prp_ans/prp_ans_tsk_hunke.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A19 output ${DATA}/prp/prp_ans/prp_ans_tsk_koch.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A20 output ${DATA}/prp/prp_ans/prp_ans_tsk_painter.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A20 output ${DATA}/prp/prp_ans/prp_ans_tsk_rasch.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A21 output ${DATA}/prp/prp_ans/prp_ans_tsk_warren.pdf

# Divvy up master PDF into FastLane components
pdftk A=${DATA}/ps/prp_ans.pdf cat A4 output ${DATA}/prp/prp_ans/prp_ans_smr.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A5-19 output ${DATA}/prp/prp_ans/prp_ans_dsc.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A20-25 output ${DATA}/prp/prp_ans/prp_ans_rfr.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A26-27 output ${DATA}/prp/prp_ans/prp_ans_bdg_jst.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A28 output ${DATA}/prp/prp_ans/prp_ans_fcl.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A29-30 output ${DATA}/prp/prp_ans/prp_ans_abb.pdf
pdftk A=${DATA}/ps/prp_ans.pdf cat A31 output ${DATA}/prp/prp_ans/prp_ans_clb.pdf

# Add letters of support in one command rather than loop
# pdftk does not allow input file to be output file
pdftk \
A=${DATA}/prp/prp_ans/prp_ans_ltr_domine.pdf \
B=${DATA}/prp/prp_ans/prp_ans_ltr_hunke.pdf \
C=${DATA}/prp/prp_ans/prp_ans_ltr_koch.pdf \
D=${DATA}/prp/prp_ans/prp_ans_ltr_rasch.pdf \
E=${DATA}/prp/prp_ans/prp_ans_ltr_warren.pdf \
F=${DATA}/prp/prp_ans/prp_ans_ltr_polarcat.pdf \
cat A B C D E F output ${DATA}/prp/prp_ans/prp_ans_ltr.pdf

# Add supplementary files in one command rather than loop
# pdftk does not allow input file to be output file
pdftk A=${DATA}/ps/prp_ans.pdf \
B=${DATA}/prp/prp_ans/prp_ans_ltr.pdf \
C=${DATA}/prp/prp_ans/prp_ans_cv_zender.pdf \
D=${DATA}/prp/prp_ans/prp_ans_cp_zender.pdf \
cat A B C D output ${DATA}/ps/prp_ans_fll.pdf

# Suggested reviewers:
Bruce Briegleb <bruceb@ncar.ucar.edu>
Jeff Dozier <dozier@bren.ucsb.edu>
Alex Hall <alexhall@atmos.ucla.edu>
Mark Jacobson <jacobson@stanford.edu>
Bonnie Light <bonnie@apl.washington.edu>
} % end csznote on proposal preparation

\csznote{
% Usage: Place usage here at end of file so comment character % not needed
cd ~/prp_ans;make -W prp_ans.tex prp_ans.dvi prp_ans.ps prp_ans.pdf prp_ans.txt;cd -
scp ${HOME}/prp_ans/prp_ans.dvi ${DATA}/ps/prp_ans.pdf ${DATA}/ps/prp_ans.ps ${HOME}/prp_ans/prp_ans.tex ${HOME}/prp_ans/prp_ans.txt dust.ess.uci.edu:/var/www/html/prp/prp_ans

# NB: latex2html works well on prp_ans.tex
latex2html -dir /var/www/html/prp/prp_ans prp_ans.tex
# NB: tth chokes on prp_ans.tex
cd ${HOME}/prp_ans;tth -a -Lprp_ans -p./:${TEXINPUTS}:${BIBINPUTS} < ${HOME}/prp_ans/prp_ans.tex > prp_ans.html
scp prp_ans.html dust.ess.uci.edu:/var/www/html/prp/prp_ans
# NB: tex4ht works well on prp_ans.tex
cd ${HOME}/prp_ans;htlatex prp_ans.tex
scp prp_ans*.css prp_ans*.html dust.ess.uci.edu:/var/www/html/prp/prp_ans
# NB: tex4moz works well on prp_ans.tex
cd ${HOME}/prp_ans;/usr/share/tex4ht/mzlatex prp_ans.tex
scp prp_ans*.css prp_ans*.html prp_ans*.xml dust.ess.uci.edu:/var/www/html/prp/prp_ans
} % end csznote on usage

\end{document}
